煤粉抑尘发泡剂的制备

IF 0.3 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemical Bulletin of Kazakh National University Pub Date : 2019-09-30 DOI:10.15328/cb1071
Z. Ospanova, S. Toktagul, A. Tasmagambetova, M. Asadov
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引用次数: 0

摘要

给出了固体煤颗粒稳定泡沫的研究结果。沉降分析法确定了最有可能的煤颗粒半径等于20.28微米。发泡能力由通过在1分钟内发泡的方法获得的泡沫柱的高度来确定。泡沫稳定性由泡沫柱完全破坏的时间来确定。在疏水性煤固体颗粒存在的情况下,由阴离子表面活性剂——十二烷基硫酸钠(DDSNa)和磺基醇(SF)与聚乙烯醇(PVA)的组合物稳定的泡沫显示出比单个表面活性剂泡沫更大的发泡能力和稳定性。获得了表面活性剂、PVA及其混合物水溶液的表面张力等温线。在煤颗粒存在下泡沫稳定性的增加对应于液气界面处的表面张力的降低。由表面活性剂PVA组合物获得的泡沫的稳定性通过稳定性因素的热力学(表面张力的降低)和结构-机械(膜间流体粘度的增加)的综合影响来解释。泡沫的这些特性可用于抑制煤矿开采中的粉尘。
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Preparation of foaming agents for dust suppression of coal particles
The results of the study of foams stabilized by solid coal particles are given. The method of sedimentation analysis determined the most likely radius of coal particles equal to 20.28 microns. Foaming ability was determined by the height of the foam column obtained by the method of bubbling within 1 min. Foam stability was determined by the time of complete destruction of the foam column. Foams stabilized by the compositions of anionic surfactants – sodium dodecyl sulfate (DDSNa) and sulfonol (SF) with polyvinyl alcohol (PVA) in the presence of hydrophobic solid particles of coal showed greater foaming capacity and stability compared to foams from individual surfactants. The surface tension isotherms of aqueous solutions of surfactants, PVA, and their mixtures were obtained. An increase in the stability of foams in the presence of coal particles corresponds to a decrease in the surface tension at the liquid-gas interface. The stability of foams obtained from surfactant-PVA compositions is explained by the combined influence of thermodynamic (reduction of surface tension) and structural-mechanical (increase in viscosity of inter-membrane fluid) of stability factors. These properties of foams can be used to suppress dust in coal mining.
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发文量
17
审稿时长
10 weeks
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