反常扩散中粒子捕获与非均质性的相互作用

IF 5.4 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Communications Physics Pub Date : 2023-09-08 DOI:10.1038/s42005-023-01365-z
Haroldo V. Ribeiro, Angel A. Tateishi, Ervin K. Lenzi, Richard L. Magin, Matjaž Perc
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引用次数: 0

摘要

异质介质的扩散通常使用与位置有关的扩散系数来描述,并通过实验中的平均位移平方来间接估算。这种方法可能会忽略其他机制及其与位置相关扩散的相互作用,从而可能导致错误的结论。在这里,我们引入了一种混合扩散模型,它将依赖位置的扩散系数与梳状模型的捕获机制合并在一起。我们推导出了位置分布和均方位移的精确解,并通过模拟朗格文方程进行了验证。我们的模型表明,捕获机制减弱了介质异质性的影响。当与位置有关的系数超线性增加时,就会出现超扩散,而当出现亚线性和反幂律关系时,就会出现亚扩散。异质性与状态无关机制之间的这种非对称相互作用还导致了反常但布朗和非布朗但高斯状态。这些发现强调了对实验进行谨慎解释的必要性,并突出了仅依赖于位移均方差或位置分布进行扩散表征的局限性。与位置相关的扩散系数通常是通过均方位移间接估算的。作者提出了一个融合了位置相关系数和梳状捕集机制的扩散模型,揭示了粒子捕集可减轻介质异质性的影响,因此在实验解释中需要谨慎。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Interplay between particle trapping and heterogeneity in anomalous diffusion
Heterogeneous media diffusion is often described using position-dependent diffusion coefficients and estimated indirectly through mean squared displacement in experiments. This approach may overlook other mechanisms and their interaction with position-dependent diffusion, potentially leading to erroneous conclusions. Here, we introduce a hybrid diffusion model that merges a position-dependent diffusion coefficient with the trapping mechanism of the comb model. We derive exact solutions for position distributions and mean squared displacements, validated through simulations of Langevin equations. Our model shows that the trapping mechanism attenuates the impact of media heterogeneity. Superdiffusion occurs when the position-dependent coefficient increases superlinearly, while subdiffusion occurs for sublinear and inverse power-law relations. This nontrivial interplay between heterogeneity and state-independent mechanisms also leads to anomalous yet Brownian, and non-Brownian yet Gaussian regimes. These findings emphasize the need for cautious interpretations of experiments and highlight the limitations of relying solely on mean squared displacements or position distributions for diffusion characterization. Position dependent diffusion coefficients are often estimated indirectly through mean square displacement. The authors propose a diffusion model merging position-dependent coefficients and comb-like trapping mechanisms, revealing that particle trapping mitigates the impact of media heterogeneity and that thus caution is needed in experimental interpretations.
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来源期刊
Communications Physics
Communications Physics Physics and Astronomy-General Physics and Astronomy
CiteScore
8.40
自引率
3.60%
发文量
276
审稿时长
13 weeks
期刊介绍: Communications Physics is an open access journal from Nature Research publishing high-quality research, reviews and commentary in all areas of the physical sciences. Research papers published by the journal represent significant advances bringing new insight to a specialized area of research in physics. We also aim to provide a community forum for issues of importance to all physicists, regardless of sub-discipline. The scope of the journal covers all areas of experimental, applied, fundamental, and interdisciplinary physical sciences. Primary research published in Communications Physics includes novel experimental results, new techniques or computational methods that may influence the work of others in the sub-discipline. We also consider submissions from adjacent research fields where the central advance of the study is of interest to physicists, for example material sciences, physical chemistry and technologies.
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