金纳米颗粒在陶瓷釉料中的降解和重整的多尺度研究

IF 2.2 4区 工程技术 Q2 Chemistry Gold Bulletin Pub Date : 2018-06-06 DOI:10.1007/s13404-018-0230-7
Nathan NL. Dinh, Luke T. DiPasquale, Michael C. Leopold, Ryan H. Coppage
{"title":"金纳米颗粒在陶瓷釉料中的降解和重整的多尺度研究","authors":"Nathan NL. Dinh,&nbsp;Luke T. DiPasquale,&nbsp;Michael C. Leopold,&nbsp;Ryan H. Coppage","doi":"10.1007/s13404-018-0230-7","DOIUrl":null,"url":null,"abstract":"<p>Most traditional ceramic glazes employ high amounts of transition metal colorants that are toxic to the environment and can cause health issues in humans through surface leaching. Gold nanoparticles (Au-NPs) have been found to be environmentally friendly and non-toxic alternative metal colorant in ceramic glazes. The plasmon band observed with Au-NPs can result in vibrant solutions by manipulating NP size, shape, and concentration; however, the effects of traditional firing in both reductive and oxidative kilns on Au-NPs are poorly understood. Aside from ancient art processes whose mechanisms have not been fully explored, the use of Au-NPs as suspended ceramic glaze colorants remains somewhat unexplored. Au-NPs have been previously reported to diminish in size during sintering and possess significant differences in concentration with respect to reduction and oxidation firing atmospheres. As a means of studying possible degradation/renucleation processes within the glaze during firing, a systematic study introducing different diameter Au-NPs into the glaze materials was conducted with transmission electron microscopy and reflectance spectroscopy used to probe possible mechanisms which showed changes to Au-NP diameter and color intensity, making this work applicable to industry and art current practices.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"51 3","pages":"75 - 83"},"PeriodicalIF":2.2000,"publicationDate":"2018-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-018-0230-7","citationCount":"2","resultStr":"{\"title\":\"A multi-size study of gold nanoparticle degradation and reformation in ceramic glazes\",\"authors\":\"Nathan NL. Dinh,&nbsp;Luke T. DiPasquale,&nbsp;Michael C. Leopold,&nbsp;Ryan H. Coppage\",\"doi\":\"10.1007/s13404-018-0230-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Most traditional ceramic glazes employ high amounts of transition metal colorants that are toxic to the environment and can cause health issues in humans through surface leaching. Gold nanoparticles (Au-NPs) have been found to be environmentally friendly and non-toxic alternative metal colorant in ceramic glazes. The plasmon band observed with Au-NPs can result in vibrant solutions by manipulating NP size, shape, and concentration; however, the effects of traditional firing in both reductive and oxidative kilns on Au-NPs are poorly understood. Aside from ancient art processes whose mechanisms have not been fully explored, the use of Au-NPs as suspended ceramic glaze colorants remains somewhat unexplored. Au-NPs have been previously reported to diminish in size during sintering and possess significant differences in concentration with respect to reduction and oxidation firing atmospheres. As a means of studying possible degradation/renucleation processes within the glaze during firing, a systematic study introducing different diameter Au-NPs into the glaze materials was conducted with transmission electron microscopy and reflectance spectroscopy used to probe possible mechanisms which showed changes to Au-NP diameter and color intensity, making this work applicable to industry and art current practices.</p>\",\"PeriodicalId\":55086,\"journal\":{\"name\":\"Gold Bulletin\",\"volume\":\"51 3\",\"pages\":\"75 - 83\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2018-06-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s13404-018-0230-7\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Gold Bulletin\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13404-018-0230-7\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Gold Bulletin","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13404-018-0230-7","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 2

摘要

大多数传统陶瓷釉料使用大量的过渡金属着色剂,这些着色剂对环境有毒,并可能通过表面浸出导致人类健康问题。金纳米颗粒(Au-NPs)是一种环保无毒的陶瓷釉料替代金属着色剂。用Au-NPs观察到的等离子体带可以通过操纵NP的大小、形状和浓度来产生充满活力的溶液;然而,传统的还原窑和氧化窑烧制对Au-NPs的影响尚不清楚。除了其机制尚未充分探索的古代艺术过程外,使用Au-NPs作为悬浮陶瓷釉色剂仍未得到充分探索。以前报道过Au-NPs在烧结过程中尺寸减小,并且在还原和氧化烧制气氛中具有显著的浓度差异。作为研究烧成过程中釉内可能的降解/再成核过程的一种手段,采用透射电子显微镜和反射光谱法对不同直径的Au-NP引入釉材料进行了系统的研究,以探索Au-NP直径和颜色强度变化的可能机制,使这项工作适用于工业和艺术当前的实践。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
A multi-size study of gold nanoparticle degradation and reformation in ceramic glazes

Most traditional ceramic glazes employ high amounts of transition metal colorants that are toxic to the environment and can cause health issues in humans through surface leaching. Gold nanoparticles (Au-NPs) have been found to be environmentally friendly and non-toxic alternative metal colorant in ceramic glazes. The plasmon band observed with Au-NPs can result in vibrant solutions by manipulating NP size, shape, and concentration; however, the effects of traditional firing in both reductive and oxidative kilns on Au-NPs are poorly understood. Aside from ancient art processes whose mechanisms have not been fully explored, the use of Au-NPs as suspended ceramic glaze colorants remains somewhat unexplored. Au-NPs have been previously reported to diminish in size during sintering and possess significant differences in concentration with respect to reduction and oxidation firing atmospheres. As a means of studying possible degradation/renucleation processes within the glaze during firing, a systematic study introducing different diameter Au-NPs into the glaze materials was conducted with transmission electron microscopy and reflectance spectroscopy used to probe possible mechanisms which showed changes to Au-NP diameter and color intensity, making this work applicable to industry and art current practices.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Gold Bulletin
Gold Bulletin 工程技术-材料科学:综合
CiteScore
3.30
自引率
4.50%
发文量
0
审稿时长
3 months
期刊介绍: Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.
期刊最新文献
Efficacy of Au versus Au–Pd nanoparticles towards synthesis of spirooxindoles via multicomponent reaction 18 Karat yellow gold single-tracks manufactured by Laser Powder Bed Fusion (LPBF): 1 064 nm and 515 nm laser comparison Microbial-mediated synthesis of gold nanoparticles—current insights and future vistas Drug release properties of amphoteric HES/p(AETAC-co-IA) hydrogels decorated with gold nanoparticles Excited-state gold catalyzed activation of inert C–Cl bonds
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1