原油与煤协同加工技术的研究与应用

IF 0.7 4区 工程技术 Q4 CHEMISTRY, APPLIED Polish Journal of Chemical Technology Pub Date : 2022-12-01 DOI:10.2478/pjct-2022-0027
Su-fang Li, Qi Liu, Q. Deng, H. Ye, Xuejie Zhou, Aijun Qiao
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引用次数: 0

摘要

研究了工艺条件对原油和煤共加工工艺的影响。通过实验室和中试研究,获得了原油/煤的匹配性能、溶胀度、原油/煤浆的粘温特性和工艺参数。共处理的最佳反应温度为445~450℃,压力为19MPa,催化剂添加量为3wt%,反应时间为2h,氢与原油的比例为1500(V/V)。此外,还开发了基于淤浆床加氢的共处理技术,包括催化剂和相应的设备。利用该共处理技术,原油和煤的进料比可以达到1:1,煤的转化率可以达到99%以上,轻质油(油和芳烃)的产率可以达到70%以上,最终产品为汽油、柴油、喷气燃料、芳烃和液化石油气。产品质量符合欧V标准,芳烃占轻质油的48%。因此,以1:1的比例对原油和煤进行共精炼是可行的。此外,对浆床加氢装置及其设备进行了长期运行测试,证明该共处理技术可以作为大规模的工业应用。
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Investigation of the co-processing technology of crude oil and coal and its deployment
Abstract The effect of process conditions on the co-processing technology of crude oil and coal was investigated. Crude oil/coal matching performance, swelling degree, crude oil/coal slurry viscosity-temperature characteristics and process parameters were obtained via the laboratory scale and pilot scale studies. The optimum reaction temperature of the co-processing was 445~450 oC, the pressure was 19 MPa, the catalyst addition was 3 wt.%, the reaction time was 2 h, and the ratio of hydrogen to crude oil was 1500 (V/V). Furthermore, the co-processing technology including catalyst and corresponding equipment based on the slurry bed hydrogenation were developed. By using this co-processing technology, the feed ratio of crude oil and coal can be 1:1, the coal conversion rate can be over 99%, the light oil (oil and aromatics) yield was over 70%, and the end products were gasoline, diesel, jet fuel, aromatics and LPG. The product quality meets the Euro V standard, whilst aromatics accounted for 48% of the light oil. So it was proved to be feasible to co-refine crude oil and coal at a ratio of 1:1. What’s more, the slurry bed hydrogenation plant and its equipment were tested for long-term operation, and it has been proved that this co-processing technology could be deployed as large-scale industrial application.
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来源期刊
Polish Journal of Chemical Technology
Polish Journal of Chemical Technology CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
1.70
自引率
10.00%
发文量
22
审稿时长
4.5 months
期刊介绍: Polish Journal of Chemical Technology is a peer-reviewed, international journal devoted to fundamental and applied chemistry, as well as chemical engineering and biotechnology research. It has a very broad scope but favors interdisciplinary research that bring chemical technology together with other disciplines. All authors receive very fast and comprehensive peer-review. Additionally, every published article is promoted to researchers working in the same field.
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