不同金属电极材料在堆肥渗滤液处理中的应用

Pub Date : 2023-05-17 DOI:10.15255/kui.2022.066
L. Vrsalović, N. Vukojević Medvidović, S. Svilović, Josip Sarić
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引用次数: 1

摘要

本文研究了不同金属材料(Fe、Al和Zn合金)在电渗析(EC)处理堆肥渗滤液过程中作为牺牲阳极的情况。采用田口L9正交阵列设计,研究了四个可控因素(不同金属材料、初始pH值、搅拌速度和接触时间)对降低化学需氧量和电极质量损失的影响。COD下降幅度在75.72~92.97%之间。田口优化结果表明,降低COD的最有效因素是实验的持续时间,而电极材料是电极质量损失。锌电极在EC工艺中处理堆肥渗滤液的潜力最低,而Al和Fe电极可在酸性或微酸性环境中使用。能耗的递减顺序为:Zn>Al>Fe。在使用Al电极的EC实验中,金属电极质量损失的测量值超过了使用法拉第定律计算的理论值,而在使用Fe和Zn电极的实验中,这些差异是不显著的。
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Application of Different Metals as Electrode Material in Compost Leachate Treatment
In this paper, different metallic materials (alloys of Fe, Al, and Zn) were investigated as sacrificial anodes during electrocoag - ulation (EC) for the treatment of compost leachate. Taguchi’s L9 orthogonal array design was applied to investigate the four controllable factors (different metallic material, initial pH value, stirring speed, and contact time) on decrease of chemical oxygen demand (COD) and electrodes mass loss. COD decrease reached values in the range of 75.72–92.97 %. The Taguchi optimisation results showed that the most effective factor for decrease of COD is the duration of the experiment, while the electrode material was for electrodes mass loss. The zinc electrode showed the lowest potential for use in the EC process for treatment of compost leachate, while the Al and Fe electrodes could be used in an acid or slightly acidic environment. The following decreasing order of energy consumption was recorded: Zn > Al > Fe. The measured values of metal electrode mass loss exceeded the theoretical values calculated using Faraday’s law in EC experiments with Al electrodes, while in experiments with Fe and Zn electrodes, those differences were insignificant.
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