含硅包覆橡胶橡胶砂浆的性能

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2021-05-20 DOI:10.3989/MC.2021.11620
J. Li, P. Chen, H. Cai, Y. Xu, X. Tian, C. Li, L. Cui
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引用次数: 3

摘要

研究了硅涂层橡胶对橡胶砂浆性能的影响。采用经典的Stober溶胶-凝胶法在橡胶颗粒上制备一层二氧化硅涂层,用于部分取代混凝土中的细骨料。考察了表面改性橡胶颗粒对砂浆流动性、力学强度、毛细吸水率和微观结构的影响。结果表明,橡胶颗粒上的二氧化硅涂层将橡胶颗粒之间的接触角从120°降低到103°(即17°),并使疏水性从强疏水性变为弱疏水性。通过加入表面改性橡胶颗粒,砂浆的机械强度显著提高,即从41.60%提高到44.86%(抗压强度),从7.80%提高到26.28%(抗弯强度)。此外,表面改性橡胶颗粒的加入增加了砂浆微观结构的密度,并增强了与周围浆料的界面。
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Performance of rubber mortars containing silica coated rubber
This paper investigates the influence of silica coated rubber on the performance of rubber mortars. A classical Stober sol-gel method is applied to produce a layer of silica coating on rubber particles, which is used to partially replace the fine aggregates in concrete. The effects of the surface-modified rubber particles on the flowability, mechanical strength, capillary water absorption rate, and microstructure of mortars are examined. The results show that the silica coating on the rubber particles reduces the contact angle between the rubber particles from 120° to 103° (i.e., by 17°) and changes the hydrophobic properties from strong hydrophobicity to weak hydrophobicity. The mechanical strengths of mortars are significantly improved by the incorporation of surface-modified rubber particles, i.e., from 41.60% to 44.86% (compressive strength) and from 7.80% to 26.28% (flexural strength). In addition, the incorporation of surface modified rubber particles increases the density of the mortar’s microstructure and enhances the interfaces with its surrounding pastes.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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