微波辅助有机催化C-C和C-X(杂原子)成键反应综述

IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Current Microwave Chemistry Pub Date : 2021-09-22 DOI:10.2174/2213335608666210922155503
Kantharaju Kamanna, Yamanappagouda Amaregouda
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引用次数: 1

摘要

有机催化是指专门含有碳、氢、氧、氮、硫和磷原子的小有机分子,以加速化学反应。研究人员展示了由有机催化剂催化的各种有机转化的广泛应用,由于它们对水分和空气的敏感性较小,易于富集,污染少,不干扰最终产品并且价格低廉。与其他传统的过渡金属和酶催化剂相比,这突出了在医药中间体和精细化学品制造中的高需求和直接效益。本文综述了微波加速有机催化碳-碳和碳杂原子成键反应的文献报道。
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Microwave-assisted organo-catalyzed C-C and C-X (heteroatom) bond-forming reactions-An overview
Organocatalysis defines small organic molecules exclusively containing carbon, hydrogen, oxygen, nitrogen, sulfur and phosphorous atom to speed-up the chemical reactions. Researcher demonstrated large area of applications in various organic transformations catalyzed by the organocatalysts, due to their less moisture sensitivity and air, easy abundance, less polluting, not interfere with the final product and inexpensive. This highlights high demand and direct benefits in the pharmaceutical intermediate and fine chemical manufacture compared to other conventional transition metal and enzyme catalysts. This review article intends to compile literature reported application of the microwave accelerated organocatalyzed carbon-carbon and carbon–heteroatom bond formation reactions reported in the literature.
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来源期刊
Current Microwave Chemistry
Current Microwave Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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