浸没式注气对铜锍中铅的去除率

S. Wright, Shouyi Sun, S. Jahanshahi
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引用次数: 1

摘要

通过高温实验测定了低铅铜锍中铅的挥发速率和活性。在1200 ~ 1570°C的温度范围内,通过向浅槽中注入氮气,测量了铅(Cu-Fe-S)的挥发速率。熔体中铅的浓度范围为200-6 mg.kg - 1。速率数据对铅的浓度表现为一级行为。推导出的气体中铅的蒸气压与熔体中铅的浓度有关,与相似温度下的平衡数据一致。温度升高对Pb在气相中的挥发速率和总分压有较大影响。哑光品位(45-83 wt%)对挥发率没有强烈影响,但增加硫势确实对抑制挥发率有显著影响。
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Rate of removal of lead from copper matte by submerged gas injection
ABSTRACT New lead volatilisation rate and activity data in copper mattes containing low levels of Pb were determined through high-temperature experiments. Measurements on volatilisation rate of lead from mattes (Cu-Fe-S) were carried out at temperatures from 1200 to 1570°C by injection of nitrogen into shallow baths. The concentration of lead in the melts covered a range of 200–6 mg.kg−1. The rate data exhibited first order behaviour with respect to concentration of Pb. The deduced vapour pressure of Pb in the gas was found to be dependent on the concentration of the Pb in melts and in accord with the equilibrium data on mattes at similar temperatures. Increasing temperature had a strong influence on volatilisation rate and total partial pressure of Pb in the gas phase. Matte grade (45–83 wt%) does not have a strong influence on volatilisation rate, but increasing sulphur potential does have a marked impact in supressing the volatilisation rate.
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CiteScore
3.50
自引率
0.00%
发文量
6
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