{"title":"碳和不锈钢上形成的硫化铁摩擦膜的结构特征","authors":"Makoto Miyajima, Mitsuharu Yonemura, Kazuyuki Kitamura, Keishi Matsumoto, Kazuyuki Yagi","doi":"10.1002/ls.1668","DOIUrl":null,"url":null,"abstract":"<p>This study investigated tribofilm layers formed under boundary lubrication using a polysulfide additive on S45C and SUS304 steel surfaces. In the tribotests, the friction coefficient of the SUS304 disc fluctuated and increased more gradually in comparison to that of the S45C disc. The tribofilm on the S45C disc comprised the outermost and inner layers of FeS<sub>2</sub> (pyrite) and FeS (troilite), respectively. Notably, all the tribofilm layers on the SUS304 disc surface contained pyrite. The tribofilm on the SUS304 disc was weakly crystalline in the outermost layer and thinner than that on the S45C disc. The poor formation of the tribofilm on the SUS304 disc was potentially caused by the unstable friction coefficient and scuffing.</p>","PeriodicalId":18114,"journal":{"name":"Lubrication Science","volume":"36 1","pages":"22-35"},"PeriodicalIF":1.8000,"publicationDate":"2023-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural characterisation of iron sulfide tribofilms formed on carbon and stainless steels\",\"authors\":\"Makoto Miyajima, Mitsuharu Yonemura, Kazuyuki Kitamura, Keishi Matsumoto, Kazuyuki Yagi\",\"doi\":\"10.1002/ls.1668\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study investigated tribofilm layers formed under boundary lubrication using a polysulfide additive on S45C and SUS304 steel surfaces. In the tribotests, the friction coefficient of the SUS304 disc fluctuated and increased more gradually in comparison to that of the S45C disc. The tribofilm on the S45C disc comprised the outermost and inner layers of FeS<sub>2</sub> (pyrite) and FeS (troilite), respectively. Notably, all the tribofilm layers on the SUS304 disc surface contained pyrite. The tribofilm on the SUS304 disc was weakly crystalline in the outermost layer and thinner than that on the S45C disc. The poor formation of the tribofilm on the SUS304 disc was potentially caused by the unstable friction coefficient and scuffing.</p>\",\"PeriodicalId\":18114,\"journal\":{\"name\":\"Lubrication Science\",\"volume\":\"36 1\",\"pages\":\"22-35\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-07-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Lubrication Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ls.1668\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Lubrication Science","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ls.1668","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Structural characterisation of iron sulfide tribofilms formed on carbon and stainless steels
This study investigated tribofilm layers formed under boundary lubrication using a polysulfide additive on S45C and SUS304 steel surfaces. In the tribotests, the friction coefficient of the SUS304 disc fluctuated and increased more gradually in comparison to that of the S45C disc. The tribofilm on the S45C disc comprised the outermost and inner layers of FeS2 (pyrite) and FeS (troilite), respectively. Notably, all the tribofilm layers on the SUS304 disc surface contained pyrite. The tribofilm on the SUS304 disc was weakly crystalline in the outermost layer and thinner than that on the S45C disc. The poor formation of the tribofilm on the SUS304 disc was potentially caused by the unstable friction coefficient and scuffing.
期刊介绍：
Lubrication Science is devoted to high-quality research which notably advances fundamental and applied aspects of the science and technology related to lubrication. It publishes research articles, short communications and reviews which demonstrate novelty and cutting edge science in the field, aiming to become a key specialised venue for communicating advances in lubrication research and development.
Lubrication is a diverse discipline ranging from lubrication concepts in industrial and automotive engineering, solid-state and gas lubrication, micro & nanolubrication phenomena, to lubrication in biological systems. To investigate these areas the scope of the journal encourages fundamental and application-based studies on:
Synthesis, chemistry and the broader development of high-performing and environmentally adapted lubricants and additives.
State of the art analytical tools and characterisation of lubricants, lubricated surfaces and interfaces.
Solid lubricants, self-lubricating coatings and composites, lubricating nanoparticles.
Gas lubrication.
Extreme-conditions lubrication.
Green-lubrication technology and lubricants.
Tribochemistry and tribocorrosion of environment- and lubricant-interface interactions.
Modelling of lubrication mechanisms and interface phenomena on different scales: from atomic and molecular to mezzo and structural.
Modelling hydrodynamic and thin film lubrication.
All lubrication related aspects of nanotribology.
Surface-lubricant interface interactions and phenomena: wetting, adhesion and adsorption.
Bio-lubrication, bio-lubricants and lubricated biological systems.
Other novel and cutting-edge aspects of lubrication in all lubrication regimes.
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