α-天使内酯聚合热力学

Cogent Chemistry Pub Date : 2018-01-01 DOI:10.1080/23312009.2018.1443689

K. L. Kaygorodov, V. Tarabanko, N. Tarabanko

{"title":"α-天使内酯聚合热力学","authors":"K. L. Kaygorodov, V. Tarabanko, N. Tarabanko","doi":"10.1080/23312009.2018.1443689","DOIUrl":null,"url":null,"abstract":"Abstract Thermodynamics of sodium butoxide-catalyzed polymerization of α-angelicalactone (a five-member unsaturated lactone) is studied by calorimetric methods. A polymer with Mw = 2,500 g/mol and the ratio of C–O to C–C inter-monomeric bonds 87–13% is obtained; this polymerization is characterized by the values of = −33.41 kJ/mol, = −42.69 J/(mol∙K) and = −20.68 kJ/mol. This and similar polymers and copolymers are biodegradable and can be produced from commercially available green bio-platform feedstock: renewable carbohydrates and levulinic acid.","PeriodicalId":10640,"journal":{"name":"Cogent Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/23312009.2018.1443689","citationCount":"6","resultStr":"{\"title\":\"Thermodynamics of α-angelicalactone polymerization\",\"authors\":\"K. L. Kaygorodov, V. Tarabanko, N. Tarabanko\",\"doi\":\"10.1080/23312009.2018.1443689\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Thermodynamics of sodium butoxide-catalyzed polymerization of α-angelicalactone (a five-member unsaturated lactone) is studied by calorimetric methods. A polymer with Mw = 2,500 g/mol and the ratio of C–O to C–C inter-monomeric bonds 87–13% is obtained; this polymerization is characterized by the values of = −33.41 kJ/mol, = −42.69 J/(mol∙K) and = −20.68 kJ/mol. This and similar polymers and copolymers are biodegradable and can be produced from commercially available green bio-platform feedstock: renewable carbohydrates and levulinic acid.\",\"PeriodicalId\":10640,\"journal\":{\"name\":\"Cogent Chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1080/23312009.2018.1443689\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cogent Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/23312009.2018.1443689\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cogent Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/23312009.2018.1443689","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 6

摘要

摘要采用量热法研究了丁氧化钠催化α-angelicalactone(一种五元不饱和内酯)聚合的热力学。得到了分子量为2500 g/mol、C-O / C-C单体间键比为87-13%的聚合物;聚合反应的表征值分别为= - 33.41 kJ/mol、= - 42.69 J/(mol∙K)和= - 20.68 kJ/mol。这种聚合物和类似的聚合物和共聚物是可生物降解的，可以从商业上可用的绿色生物平台原料:可再生碳水化合物和乙酰丙酸生产。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Thermodynamics of α-angelicalactone polymerization

Abstract Thermodynamics of sodium butoxide-catalyzed polymerization of α-angelicalactone (a five-member unsaturated lactone) is studied by calorimetric methods. A polymer with Mw = 2,500 g/mol and the ratio of C–O to C–C inter-monomeric bonds 87–13% is obtained; this polymerization is characterized by the values of = −33.41 kJ/mol, = −42.69 J/(mol∙K) and = −20.68 kJ/mol. This and similar polymers and copolymers are biodegradable and can be produced from commercially available green bio-platform feedstock: renewable carbohydrates and levulinic acid.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Cogent Chemistry CHEMISTRY, MULTIDISCIPLINARY-

自引率

0.00%

发文量