用于腐蚀研究的扫描电化学显微镜方法(SECM)和离子选择性微电极

IF 2.7 4区 材料科学 Q3 ELECTROCHEMISTRY Corrosion Reviews Pub Date : 2022-07-08 DOI:10.1515/corrrev-2021-0104
I. Traxler, T. D. Singewald, G. Schimo-Aichhorn, S. Hild, M. Valtiner
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引用次数: 5

摘要

摘要近30年来,扫描电化学显微镜(SECM)已成为腐蚀研究的基础技术。凭借其高空间分辨率和研究局部电化学的能力,它在本质上有助于理解腐蚀过程。通过使用选择性的微米和纳米传感器,可以建立从质子到金属离子的不同腐蚀相关物种的浓度分布。这篇综述全面概述了基于SECM的技术,讨论了各种类型的微传感器,包括材料选择和制备技术,并为特定的腐蚀研究应用提供了大量的氧化还原偶表。
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Scanning electrochemical microscopy methods (SECM) and ion-selective microelectrodes for corrosion studies
Abstract Over the last 30 years, scanning electrochemical microscopy (SECM) has become a fundamental technique in corrosion research. With its high spatial resolution and its ability to study local electrochemistry, it contributes essentially to the understanding of corrosion processes. By using selective micro- and nano-sensors, concentration profiles of different corrosion relevant species, from protons to metal ions, can be established. This review provides a comprehensive overview about SECM based techniques and discusses various types of microsensors, including materials selection and preparation techniques, and it provides extensive tables on redox-couples for specific corrosion research applications.
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来源期刊
Corrosion Reviews
Corrosion Reviews 工程技术-材料科学:膜
CiteScore
5.20
自引率
3.10%
发文量
44
审稿时长
4.5 months
期刊介绍: Corrosion Reviews is an international bimonthly journal devoted to critical reviews and, to a lesser extent, outstanding original articles that are key to advancing the understanding and application of corrosion science and engineering in the service of society. Papers may be of a theoretical, experimental or practical nature, provided that they make a significant contribution to knowledge in the field.
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