分子氧与水光催化合成过氧化氢的研究

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2023-05-09 DOI:10.1007/s41061-023-00423-y
Patricia Garcia-Munoz, Laura Valenzuela, Deborah Wegstein, Tobias Schanz, Girlie Eunice Lopez, Agnieszka M. Ruppert, Hynd Remita, Jonathan Z. Bloh, Nicolas Keller
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引用次数: 0

摘要

过氧化氢是一种强大的绿色氧化剂,它允许在温和的反应条件下氧化液体介质中广泛的有机和无机底物,并且只形成分子水和氧作为最终产物。因此,过氧化氢在广泛的应用中得到了广泛的应用,其中有充分记录和建立的蒽醌自氧化工艺是迄今为止工业规模上的主要生产方法。由于这种方法耗能大,环境成本高,因此寻找更可持续的合成方法是人们高度关注的问题。为此,本文综述了光催化合成过氧化氢的基础和最新进展。讨论了不同的氧还原和水氧化机理,以及几种动力学模型,并列举了主要关键反应参数的影响。综述了大量的光催化材料,重点介绍了钛基光催化剂和具有高前景的石墨氮化碳基系统,它们利用了先进的体和表面合成方法。报告了提高太阳能驱动光催化剂性能的策略,并详细介绍了寻找新的替代光催化材料的情况。最后,介绍了原位光催化合成过氧化氢用于水处理和有机合成的前景,以及它与酶的偶联和其他技术过氧化物的直接原位合成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Photocatalytic Synthesis of Hydrogen Peroxide from Molecular Oxygen and Water

Hydrogen peroxide is a powerful and green oxidant that allows for the oxidation of a wide span of organic and inorganic substrates in liquid media under mild reaction conditions, and forms only molecular water and oxygen as end products. Hydrogen peroxide is therefore used in a wide range of applications, for which the well-documented and established anthraquinone autoxidation process is by far the dominating production method at the industrial scale. As this method is highly energy consuming and environmentally costly, the search for more sustainable synthesis methods is of high interest. To this end, the article reviews the basis and the recent development of the photocatalytic synthesis of hydrogen peroxide. Different oxygen reduction and water oxidation mechanisms are discussed, as well as several kinetic models, and the influence of the main key reaction parameters is itemized. A large range of photocatalytic materials is reviewed, with emphasis on titania-based photocatalysts and on high-prospect graphitic carbon nitride-based systems that take advantage of advanced bulk and surface synthetic approaches. Strategies for enhancing the performances of solar-driven photocatalysts are reported, and the search for new, alternative, photocatalytic materials is detailed. Finally, the promise of in situ photocatalytic synthesis of hydrogen peroxide for water treatment and organic synthesis is described, as well as its coupling with enzymes and the direct in situ synthesis of other technical peroxides.

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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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