{"title":"粘性和粘弹性流体等温毛细管流变法压降的数值研究","authors":"H. Tseng","doi":"10.1515/ipp-2022-4322","DOIUrl":null,"url":null,"abstract":"Abstract In capillary rheometry of a polymer melt, the total pressure drop consists of three primary components: shear viscosity, extensional viscosity, and normal stress differences. Traditionally, viscoelastic constitutive equations have been used to produce accurate predictions regarding the pressure drop. It is difficult to investigate the primary components in past experimental measurements and numerical computations. The useful improvement of the classic White-Metzner viscoelastic constitutive equation coupled with the weighted shear/extension viscosity is performed in isothermal capillary flow simulations. It is significant to analyze the extension-induced pressure drop for a short die and the shear-induced pressure drop for a long die, along with a small contribution of normal stress differences.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Numerical investigation of pressure drop within isothermal capillary rheometry for viscous and viscoelastic fluids\",\"authors\":\"H. Tseng\",\"doi\":\"10.1515/ipp-2022-4322\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract In capillary rheometry of a polymer melt, the total pressure drop consists of three primary components: shear viscosity, extensional viscosity, and normal stress differences. Traditionally, viscoelastic constitutive equations have been used to produce accurate predictions regarding the pressure drop. It is difficult to investigate the primary components in past experimental measurements and numerical computations. The useful improvement of the classic White-Metzner viscoelastic constitutive equation coupled with the weighted shear/extension viscosity is performed in isothermal capillary flow simulations. It is significant to analyze the extension-induced pressure drop for a short die and the shear-induced pressure drop for a long die, along with a small contribution of normal stress differences.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1515/ipp-2022-4322\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1515/ipp-2022-4322","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Numerical investigation of pressure drop within isothermal capillary rheometry for viscous and viscoelastic fluids
Abstract In capillary rheometry of a polymer melt, the total pressure drop consists of three primary components: shear viscosity, extensional viscosity, and normal stress differences. Traditionally, viscoelastic constitutive equations have been used to produce accurate predictions regarding the pressure drop. It is difficult to investigate the primary components in past experimental measurements and numerical computations. The useful improvement of the classic White-Metzner viscoelastic constitutive equation coupled with the weighted shear/extension viscosity is performed in isothermal capillary flow simulations. It is significant to analyze the extension-induced pressure drop for a short die and the shear-induced pressure drop for a long die, along with a small contribution of normal stress differences.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.