希夫碱金属钌配合物的合成与应用

IF 8.6 2区 化学 Q1 Chemistry Topics in Current Chemistry Pub Date : 2021-06-10 DOI:10.1007/s41061-021-00342-w
Anmol Singh, Pranjit Barman
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引用次数: 29

摘要

本文综述了钌希夫碱的最新研究进展,通过选择合适的缩合醛或酮和伯胺及其金属配合物,可以很容易地控制其空间和电子特性。钌金属配合物和希夫碱配体正迅速成为传统的生物应用(抗氧化、抗癌、抗菌)、催化、功能材料、传感器和染料颜料。钌配合物在简单的希夫碱配体上表现出多种活性。这可能是由于Ru(II)和Ru(III)配合物的八面体键合,它们获得了一个扩展的三维框架储存库,为结合其生物靶标提供了更高程度的位点选择性。本文综述了这一领域的研究进展,重点介绍了配体设计和合成方法的发展,以及这些金属配合物的重要应用。本文对近年来钌配合物的研究进展进行了综述。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent Advances in Schiff Base Ruthenium Metal Complexes: Synthesis and Applications

This review concentrates on recent developments in ruthenium Schiff bases, whose steric and electronic characteristics can be manipulated easily by selecting suitable condensing aldehydes or ketones and primary amines, and their metal complexes. Ruthenium metal-based complexes and Schiff base ligands are rapidly becoming conventionally considered for biological applications (antioxidant, anticancer, antimicrobial), in catalysis, in functional materials, in sensors, and as pigments for dyes. Ruthenium complexes exhibit a broad variety of activities concerning simple Schiff base ligands. This may be due to the octahedral bonding of both Ru(II) and Ru(III) complexes, which acquire an extended reservoir of a three-dimensional framework, providing the potential for an elevated degree of site selectivity for binding to their biological targets. This review provides an overview of this field, and intends to highlight both ligand design and synthetic methodology development, as well as significant applications of these metal complexes. In this review, we summarize our work on the development of ruthenium complexes, which was performed over the last few years.

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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry 化学-化学综合
CiteScore
11.70
自引率
1.20%
发文量
0
审稿时长
6-12 weeks
期刊介绍: Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.
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