基于多静电纺丝纳米纤维传感器阵列的电子鼻及其在气体分类中的应用

Chuanlai Zang, Hao-Long Zhou, K. Ma, Y. Yano, Shuowei Li, H. Yamahara, M. Seki, Tetsuya Iizuka, H. Tabata
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引用次数: 1

摘要

为了模拟人类的嗅觉系统,提出了一种基于多气体传感器阵列和模式识别算法的电子鼻(E-nose,又称人工嗅觉)。挥发性有机成分(VOCs)的检测在呼吸分析、食品质量评价、室内外空气质量监测等方面具有广泛的应用前景。在本研究中,采用简单的单针静电纺丝技术制备了四种不同半导体金属氧化物(MOS)纳米纤维传感器阵列(分别为SnO2, CuO, In2O3和ZnO)。该阵列具有光滑的表面和恒定直径的纳米纤维(平均为150 nm),对多种目标分析气体具有高灵敏度。利用自制的电子鼻对5种与人体健康相关的挥发性有机化合物气体进行了测量,从4种MOS纳米纤维传感器获得了不同的响应模式。结合响应曲线的特征提取,采用主成分分析(PCA)算法对特征矩阵进行降维处理,使电子鼻系统成功识别出5种不同的VOCs气体。电子鼻实时、无创气体监测在人体健康监测、食品监测等领域具有广阔的应用前景。
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Electronic nose based on multiple electrospinning nanofibers sensor array and application in gas classification
To mimic the human olfactory system, an electronic nose (E-nose, also known as artificial olfactory) has been proposed based on a multiple gas sensor array and a pattern recognition algorithm. Detection of volatile organic components (VOCs) has many potential applications in breath analysis, food quality estimation, and indoor and outdoor air quality monitoring, etc. In this study, a facile single-needle electrospinning technology was applied to develop the four different semiconductor metal oxide (MOS) nanofibers sensor arrays (SnO2, CuO, In2O3 and ZnO, respectively). The array shows a smooth surface and constant diameter of nanofiber (average of 150 nm) resulting in high sensitivity to multiple target analyte gases. Five human health related VOCs gases were measured by fabricated E-nose and different response patterns were obtained from four MOS nanofibers sensors. Combined with feature extraction from the response curves, a principal component analysis (PCA) algorithm was applied to reduce the dimension of feature matrix, Thus, the fabricated E-nose system successfully discriminated five different VOCs gases. Real-time and non-invasive gas monitoring by E-nose is very promising for application in human health monitoring, food monitoring, and other fields.
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