具有强而长寿命激发态吸收的过渡金属配合物:从分子设计到光功率限制行为

IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Reviews in Inorganic Chemistry Pub Date : 2022-08-22 DOI:10.1515/revic-2022-0013
H. Su, Lai Hu, Senqiang Zhu, Jiapeng Lu, Jinyang Hu, Rui Liu, Hongjun Zhu
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引用次数: 1

摘要

摘要具有强、长寿命激发态吸收(ESA)的过渡金属配合物(TMCs)通常表现出高性能的光功率限制(OPL)响应。一些技术,如透射与入射通量曲线和Z扫描,已被广泛用于评估典型TMC的OPL性能。TMCs的OPL性能高度依赖于分子结构。特别强调了Pt(II)、Ir(III)、Ru(Ⅱ)和其他金属配合物的结构-OPL响应关系。这篇综述的结尾是对OPL领域现状的展望,以及其前沿之外的机遇。
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Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior
Abstract Transition metal complexes (TMCs) with strong and long-lived excited state absorption (ESA) usually exhibit high-performance optical power limiting (OPL) response. Several techniques, such as transmission vs. incident fluence curves and Z-scan have been widely used to assess the OPL performance of typical TMCs. The OPL performance of TMCs is highly molecular structure-dependent. Special emphasis is placed on the structure-OPL response relationships of Pt(II), Ir(III), Ru(II), and other metal complexes. This review concludes with perspectives on the current status of OPL field, as well as opportunities that lie just beyond its frontier.
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来源期刊
Reviews in Inorganic Chemistry
Reviews in Inorganic Chemistry 化学-分析化学
CiteScore
7.30
自引率
4.90%
发文量
20
审稿时长
1 months
期刊介绍: Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids
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