{"title":"合成皮革用聚二甲基硅氧烷涂层的制备、机械性能和热性能","authors":"Zhe Sun, Jiating Wen, Jinping Guan, Haojun Fan, Jian Fang, Yi Chen, Wenkai Wang, Qiang Gao","doi":"10.1007/s11998-022-00645-7","DOIUrl":null,"url":null,"abstract":"<div><p>The curing process of polydimethylsiloxane (PDMS) coating was systematically investigated by nonisothermal differential scanning calorimeter (DSC), and accordingly, the thermodynamic as well as kinetic parameters were obtained. Meanwhile, effect of structural factors, including different divinyl-terminated polydimethylsiloxane (<sup>Vi</sup>PDMS<sup>Vi</sup>), divinyl-terminated polymethylvinylsiloxane (<sup>Vi</sup>PMVS<sup>Vi</sup>), polymethylhydrosiloxane (PMHS), and reinforcing filler content, on mechanical and thermal properties of coating was studied. The results demonstrated that platinum compounds could significantly accelerate the hydrosilylation and reduce the curing temperature and activation energy. The viscosity, vinyl/hydrogen sites, and quantities of <sup>Vi</sup>PDMS<sup>Vi</sup>, <sup>Vi</sup>PMVS<sup>Vi</sup>, and PMHS were important factors to influence mechanical and thermal properties. Low viscosity <sup>Vi</sup>PDMS<sup>Vi</sup> and PMHS with side hydrogen atoms could increase crosslinking density, and then enhance the tensile strength and heat resistance. <sup>Vi</sup>PMVS<sup>Vi</sup> with higher viscosity and vinyl content could dramatically improve tensile strength while maintaining breaking elongation. Reinforcing filler was another vital factor to enhance strength and thermostability. 550% improvement in tensile strength occurred when reinforcing filler content was 40 wt%. All aforementioned results provided a comprehensive guidance for the preparation and property regulation of PDMS coating. This kind of PDMS coating can be applied in synthetic leather manufacturing.</p><h3>Graphical abstract</h3>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":48804,"journal":{"name":"Journal of Coatings Technology and Research","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2022-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-022-00645-7.pdf","citationCount":"1","resultStr":"{\"title\":\"Preparation, mechanical and thermal properties of polydimethylsiloxane coating for synthetic leathers\",\"authors\":\"Zhe Sun, Jiating Wen, Jinping Guan, Haojun Fan, Jian Fang, Yi Chen, Wenkai Wang, Qiang Gao\",\"doi\":\"10.1007/s11998-022-00645-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The curing process of polydimethylsiloxane (PDMS) coating was systematically investigated by nonisothermal differential scanning calorimeter (DSC), and accordingly, the thermodynamic as well as kinetic parameters were obtained. Meanwhile, effect of structural factors, including different divinyl-terminated polydimethylsiloxane (<sup>Vi</sup>PDMS<sup>Vi</sup>), divinyl-terminated polymethylvinylsiloxane (<sup>Vi</sup>PMVS<sup>Vi</sup>), polymethylhydrosiloxane (PMHS), and reinforcing filler content, on mechanical and thermal properties of coating was studied. The results demonstrated that platinum compounds could significantly accelerate the hydrosilylation and reduce the curing temperature and activation energy. The viscosity, vinyl/hydrogen sites, and quantities of <sup>Vi</sup>PDMS<sup>Vi</sup>, <sup>Vi</sup>PMVS<sup>Vi</sup>, and PMHS were important factors to influence mechanical and thermal properties. Low viscosity <sup>Vi</sup>PDMS<sup>Vi</sup> and PMHS with side hydrogen atoms could increase crosslinking density, and then enhance the tensile strength and heat resistance. <sup>Vi</sup>PMVS<sup>Vi</sup> with higher viscosity and vinyl content could dramatically improve tensile strength while maintaining breaking elongation. Reinforcing filler was another vital factor to enhance strength and thermostability. 550% improvement in tensile strength occurred when reinforcing filler content was 40 wt%. All aforementioned results provided a comprehensive guidance for the preparation and property regulation of PDMS coating. This kind of PDMS coating can be applied in synthetic leather manufacturing.</p><h3>Graphical abstract</h3>\\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\\n </div>\",\"PeriodicalId\":48804,\"journal\":{\"name\":\"Journal of Coatings Technology and Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2022-07-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s11998-022-00645-7.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Coatings Technology and Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11998-022-00645-7\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Coatings Technology and Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11998-022-00645-7","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
Preparation, mechanical and thermal properties of polydimethylsiloxane coating for synthetic leathers
The curing process of polydimethylsiloxane (PDMS) coating was systematically investigated by nonisothermal differential scanning calorimeter (DSC), and accordingly, the thermodynamic as well as kinetic parameters were obtained. Meanwhile, effect of structural factors, including different divinyl-terminated polydimethylsiloxane (ViPDMSVi), divinyl-terminated polymethylvinylsiloxane (ViPMVSVi), polymethylhydrosiloxane (PMHS), and reinforcing filler content, on mechanical and thermal properties of coating was studied. The results demonstrated that platinum compounds could significantly accelerate the hydrosilylation and reduce the curing temperature and activation energy. The viscosity, vinyl/hydrogen sites, and quantities of ViPDMSVi, ViPMVSVi, and PMHS were important factors to influence mechanical and thermal properties. Low viscosity ViPDMSVi and PMHS with side hydrogen atoms could increase crosslinking density, and then enhance the tensile strength and heat resistance. ViPMVSVi with higher viscosity and vinyl content could dramatically improve tensile strength while maintaining breaking elongation. Reinforcing filler was another vital factor to enhance strength and thermostability. 550% improvement in tensile strength occurred when reinforcing filler content was 40 wt%. All aforementioned results provided a comprehensive guidance for the preparation and property regulation of PDMS coating. This kind of PDMS coating can be applied in synthetic leather manufacturing.
期刊介绍:
Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.