M. Derradji, Karim Khiari, Oussama Mehelli, S. Abdous, Abdelmalek Habes, Noureddine Ramdani, Abdeljalil Zegaoui, Wen-ben Liu, A. Daham
{"title":"香草基苯并恶嗪和硅烷表面改性短切玄武岩纤维的全绿色复合材料的力学和热性能","authors":"M. Derradji, Karim Khiari, Oussama Mehelli, S. Abdous, Abdelmalek Habes, Noureddine Ramdani, Abdeljalil Zegaoui, Wen-ben Liu, A. Daham","doi":"10.1177/09540083221143688","DOIUrl":null,"url":null,"abstract":"By following the rules of green chemistry, a novel composite is developed from a renewable and ecofriendly resource, namely the vanillin. The latter was used as a phenolic precursor for the microwave synthesis of a bio-based benzoxazine resin (Va-BZ). Afterwards, high performance green composites were developed by reinforcing the Va-BZ with various amounts of chopped silane surface modified basalt fibers (BFs). The chemical structure of the Va-BZ monomers was confirmed by 1H NMR and FTIR spectroscopy. The grafting of the silane moiety on the BFs surface was assessed by FTIR and TGA analyses. The autocatalytic ring opening polymerization of the Va-BZ monomers was confirmed by DSC analysis. The mechanical performances of the developed green composites were studied by flexural and tensile investigations. The findings suggested that the maximum amount of 20 wt. BFs afforded the best results, with flexural and tensile strengths of 447 and 460 MPa, respectively. The SEM was used to study the fractured tensile surfaces and elucidated the toughening mechanism. Meanwhile, the TGA showed that the introduction of the BFs markedly improved the thermal stability of the benzoxazine matrix. Finally, the gamma rays shielding effectiveness was studied and revealed the highly benefic role of the BFs. For instance, a 1 cm thick Va-BZ polymer only showed a 6% gamma rays screening ratio, the latter was improved to 18.4% for the composite made of 20 wt.% of treated BFs. Overall, this study confirmed that greener approaches can also result in high performance composite satisfying the needs of exigent applications.","PeriodicalId":12932,"journal":{"name":"High Performance Polymers","volume":"35 1","pages":"412 - 425"},"PeriodicalIF":1.8000,"publicationDate":"2022-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Mechanical and thermal properties of fully green composites from vanillin-based benzoxazine and silane surface modified chopped basalt fibers\",\"authors\":\"M. Derradji, Karim Khiari, Oussama Mehelli, S. Abdous, Abdelmalek Habes, Noureddine Ramdani, Abdeljalil Zegaoui, Wen-ben Liu, A. Daham\",\"doi\":\"10.1177/09540083221143688\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"By following the rules of green chemistry, a novel composite is developed from a renewable and ecofriendly resource, namely the vanillin. The latter was used as a phenolic precursor for the microwave synthesis of a bio-based benzoxazine resin (Va-BZ). Afterwards, high performance green composites were developed by reinforcing the Va-BZ with various amounts of chopped silane surface modified basalt fibers (BFs). The chemical structure of the Va-BZ monomers was confirmed by 1H NMR and FTIR spectroscopy. The grafting of the silane moiety on the BFs surface was assessed by FTIR and TGA analyses. The autocatalytic ring opening polymerization of the Va-BZ monomers was confirmed by DSC analysis. The mechanical performances of the developed green composites were studied by flexural and tensile investigations. The findings suggested that the maximum amount of 20 wt. BFs afforded the best results, with flexural and tensile strengths of 447 and 460 MPa, respectively. The SEM was used to study the fractured tensile surfaces and elucidated the toughening mechanism. Meanwhile, the TGA showed that the introduction of the BFs markedly improved the thermal stability of the benzoxazine matrix. Finally, the gamma rays shielding effectiveness was studied and revealed the highly benefic role of the BFs. For instance, a 1 cm thick Va-BZ polymer only showed a 6% gamma rays screening ratio, the latter was improved to 18.4% for the composite made of 20 wt.% of treated BFs. 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Mechanical and thermal properties of fully green composites from vanillin-based benzoxazine and silane surface modified chopped basalt fibers
By following the rules of green chemistry, a novel composite is developed from a renewable and ecofriendly resource, namely the vanillin. The latter was used as a phenolic precursor for the microwave synthesis of a bio-based benzoxazine resin (Va-BZ). Afterwards, high performance green composites were developed by reinforcing the Va-BZ with various amounts of chopped silane surface modified basalt fibers (BFs). The chemical structure of the Va-BZ monomers was confirmed by 1H NMR and FTIR spectroscopy. The grafting of the silane moiety on the BFs surface was assessed by FTIR and TGA analyses. The autocatalytic ring opening polymerization of the Va-BZ monomers was confirmed by DSC analysis. The mechanical performances of the developed green composites were studied by flexural and tensile investigations. The findings suggested that the maximum amount of 20 wt. BFs afforded the best results, with flexural and tensile strengths of 447 and 460 MPa, respectively. The SEM was used to study the fractured tensile surfaces and elucidated the toughening mechanism. Meanwhile, the TGA showed that the introduction of the BFs markedly improved the thermal stability of the benzoxazine matrix. Finally, the gamma rays shielding effectiveness was studied and revealed the highly benefic role of the BFs. For instance, a 1 cm thick Va-BZ polymer only showed a 6% gamma rays screening ratio, the latter was improved to 18.4% for the composite made of 20 wt.% of treated BFs. Overall, this study confirmed that greener approaches can also result in high performance composite satisfying the needs of exigent applications.
期刊介绍:
Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.