活性炭在Y-沸石中预浸渍Co-Mo过程中的添加方法超稳定:负载金属的性能探索和增强

Y. Hidayat, K. Nugrahaningtyas, Priska Julia Hendrastuti
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引用次数: 0

摘要

通过在预浸渍过程中添加活性炭,增加了超稳定Y沸石(USY)上负载的Co-Mo金属的量。通过向USY中添加多达10wt%的活性炭来进行USY改性。添加活性炭的过程通过三种方法进行,即用蔗糖粘合剂研磨(ACU1)、不加蔗糖研磨(ACU2)和通过球磨进行(ACU3)。采用湿式浸渍法将钴和钼依次分散。使用傅立叶变换红外光谱(FTIR)、X射线衍射(XRD)和表面积分析仪(SAA)对复合材料进行了表征。通过X射线荧光(XRF)观察金属分散体。FTIR表明USY与活性炭之间存在相互作用,XRD结果表明USY沸石没有发生结构转变。SAA分析显示,随着活性炭的加入,总孔半径增加。XRF证实总金属分散度增加6.25%(ACU1);5.48%(ACU2);5.18%(ACU3);与装载了3.28%金属的USY来源相比。
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Activated Carbon Addition Methods on the Pre-impregnation Process of Co-Mo in Y-Zeolite Ultra Stable: A Properties Exploration and Enhancement of Metals Loaded
The amount of loaded Co-Mo metal on the Y-Zeolite Ultra Stable (USY) was increased by the addition of activated carbon in the pre-impregnation process. USY modification was done by adding activated carbon to USY as much as 10 wt%. The process of adding activated carbon is carried out by three methods, i.e., grinding with sucrose binder (ACU1), without sucrose (ACU2), and conducting by ball milling (ACU3). Wet impregnation method was employed to disperse the Co and Mo, sequentially. Composites were characterized using Fourier Transform Infrared (FTIR), X-ray diffraction (XRD), and surface area analyzer (SAA). Metal dispersions were observed by X-ray fluorescence (XRF). The FTIR suggests an interaction between USY and activated car-bon, while the XRD result indicated the none structural transformation of USY zeolite. The SAA analysis showed an increased total pore radius with the activated carbon addition. The XRF confirmed the increasing of total metals dispersion of 6.25% (ACU1); 5.48%(ACU2); 5.18% (ACU3); compare to USY origin with 3.28% metals loaded.
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