{"title":"多孔Eu-PTA/Tb-SSA/ZrO2/ZnZrO3光色可调荧光粉:暖白光LED的发光性能及应用","authors":"","doi":"10.1016/j.jre.2023.07.009","DOIUrl":null,"url":null,"abstract":"<div><p>Light emitting diode (LED) is the fourth generation lighting source, but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time application. In this study, a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> (Eu-PTA/Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub>) phosphor with warm white light emission properties was prepared, and the warm white light LED (w-WLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> phosphors together with 270 nm UV-chip. The ZrO<sub>2</sub>/ZnZrO<sub>3</sub>, Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> and Eu-PTA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> samples show blue emission, green emission and red emission under deep ultraviolet (UV, 270 nm) excitation, respectively. The Tb-SSA and Eu-PTA are co-doped into ZrO<sub>2</sub>/ZnZrO<sub>3</sub> matrix with blue emission to achieve the warm white light emission, and the light color can be adjusted by controlling the doping amount of Eu<sup>3+</sup> and Tb<sup>3+</sup>. Through the excitation method of single-component phosphor by the single chip, the complex chip packaging process of w-LED can be solved. By doping rare earth organic complexes into porous ZrO<sub>2</sub>/ZnZrO<sub>3</sub> matrix, the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1421-1428"},"PeriodicalIF":7.2000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A porous Eu-PTA/Tb-SSA/ZrO2/ZnZrO3 light color adjustable phosphor: Luminescent property and application of warm white LED\",\"authors\":\"\",\"doi\":\"10.1016/j.jre.2023.07.009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Light emitting diode (LED) is the fourth generation lighting source, but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time application. In this study, a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> (Eu-PTA/Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub>) phosphor with warm white light emission properties was prepared, and the warm white light LED (w-WLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> phosphors together with 270 nm UV-chip. The ZrO<sub>2</sub>/ZnZrO<sub>3</sub>, Tb-SSA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> and Eu-PTA/ZrO<sub>2</sub>/ZnZrO<sub>3</sub> samples show blue emission, green emission and red emission under deep ultraviolet (UV, 270 nm) excitation, respectively. The Tb-SSA and Eu-PTA are co-doped into ZrO<sub>2</sub>/ZnZrO<sub>3</sub> matrix with blue emission to achieve the warm white light emission, and the light color can be adjusted by controlling the doping amount of Eu<sup>3+</sup> and Tb<sup>3+</sup>. Through the excitation method of single-component phosphor by the single chip, the complex chip packaging process of w-LED can be solved. By doping rare earth organic complexes into porous ZrO<sub>2</sub>/ZnZrO<sub>3</sub> matrix, the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.</p></div>\",\"PeriodicalId\":16940,\"journal\":{\"name\":\"Journal of Rare Earths\",\"volume\":\"42 8\",\"pages\":\"Pages 1421-1428\"},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2024-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Rare Earths\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1002072123001916\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Rare Earths","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1002072123001916","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
A porous Eu-PTA/Tb-SSA/ZrO2/ZnZrO3 light color adjustable phosphor: Luminescent property and application of warm white LED
Light emitting diode (LED) is the fourth generation lighting source, but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time application. In this study, a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO2/ZnZrO3 (Eu-PTA/Tb-SSA/ZrO2/ZnZrO3) phosphor with warm white light emission properties was prepared, and the warm white light LED (w-WLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO2/ZnZrO3 phosphors together with 270 nm UV-chip. The ZrO2/ZnZrO3, Tb-SSA/ZrO2/ZnZrO3 and Eu-PTA/ZrO2/ZnZrO3 samples show blue emission, green emission and red emission under deep ultraviolet (UV, 270 nm) excitation, respectively. The Tb-SSA and Eu-PTA are co-doped into ZrO2/ZnZrO3 matrix with blue emission to achieve the warm white light emission, and the light color can be adjusted by controlling the doping amount of Eu3+ and Tb3+. Through the excitation method of single-component phosphor by the single chip, the complex chip packaging process of w-LED can be solved. By doping rare earth organic complexes into porous ZrO2/ZnZrO3 matrix, the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.
期刊介绍：
The Journal of Rare Earths reports studies on the 17 rare earth elements. It is a unique English-language learned journal that publishes works on various aspects of basic theory and applied science in the field of rare earths (RE). The journal accepts original high-quality original research papers and review articles with inventive content, and complete experimental data. It represents high academic standards and new progress in the RE field. Due to the advantage of abundant RE resources of China, the research on RE develops very actively, and papers on the latest progress in this field emerge every year. It is not only an important resource in which technicians publish and obtain their latest research results on RE, but also an important way of reflecting the updated progress in RE research field.
The Journal of Rare Earths covers all research and application of RE rare earths including spectroscopy, luminescence and phosphors, rare earth catalysis, magnetism and magnetic materials, advanced rare earth materials, RE chemistry & hydrometallurgy, RE metallography & pyrometallurgy, RE new materials, RE solid state physics & solid state chemistry, rare earth applications, RE analysis & test, RE geology & ore dressing, etc.
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