Minhao Yang, Zhi-Yong Xue, Zhi-Min Dang, Yang Shen, Paul Haghi-Ashtiani, Delong He, Jian Xu, Jinbo Bai
{"title":"通过单独控制Core@Double - Shells结构纳米线的壳厚度来调节聚偏氟乙烯纳米复合材料的介电性能","authors":"Minhao Yang, Zhi-Yong Xue, Zhi-Min Dang, Yang Shen, Paul Haghi-Ashtiani, Delong He, Jian Xu, Jinbo Bai","doi":"10.1049/nde2.12003","DOIUrl":null,"url":null,"abstract":"<p>The synthesis of core@double-shells structured TiO<sub>2</sub>@C@SiO<sub>2</sub> nanowires (NWs) with variable thickness of carbon inner shell and SiO<sub>2</sub> outer shell was achieved by individually controlling the chemical vapour deposition time and amount of silicon precursor added in the sol–gel synthesis. The resultant TiO<sub>2</sub>@C@SiO<sub>2</sub> NWs filled nanocomposites exhibited an excellent dielectric performance with simultaneously improved dielectric constant and suppressed dielectric loss, which could be further regulated by individually controlling the carbon inner shell and SiO<sub>2</sub> outer shell thickness. More importantly, the influences of the conductive carbon inner shell and insulated SiO<sub>2</sub> outer shell thickness on the dielectric performance of nanocomposites were clearly revealed. The increase of the conductive carbon inner shell thickness would lead to an increase in dielectric constant and loss of nanocomposites, while the insulated SiO<sub>2</sub> outer shell exhibited a totally opposite law that the dielectric constant and loss of nanocomposites decrease with increasing SiO<sub>2</sub> outer shell thickness. Numerical simulations were also carried out to theoretically verify the relationship between the dielectric loss and SiO<sub>2</sub> outer shell thickness. This promising controllable multi-shell structure could be extended to a variety of hybrids to develop high-performance dielectric nanocomposites.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2021-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12003","citationCount":"4","resultStr":"{\"title\":\"Regulating dielectric performances of Poly(vinylidene fluoride) nanocomposites by individually controlling shell thickness of Core@Double-Shells structured nanowires\",\"authors\":\"Minhao Yang, Zhi-Yong Xue, Zhi-Min Dang, Yang Shen, Paul Haghi-Ashtiani, Delong He, Jian Xu, Jinbo Bai\",\"doi\":\"10.1049/nde2.12003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The synthesis of core@double-shells structured TiO<sub>2</sub>@C@SiO<sub>2</sub> nanowires (NWs) with variable thickness of carbon inner shell and SiO<sub>2</sub> outer shell was achieved by individually controlling the chemical vapour deposition time and amount of silicon precursor added in the sol–gel synthesis. The resultant TiO<sub>2</sub>@C@SiO<sub>2</sub> NWs filled nanocomposites exhibited an excellent dielectric performance with simultaneously improved dielectric constant and suppressed dielectric loss, which could be further regulated by individually controlling the carbon inner shell and SiO<sub>2</sub> outer shell thickness. More importantly, the influences of the conductive carbon inner shell and insulated SiO<sub>2</sub> outer shell thickness on the dielectric performance of nanocomposites were clearly revealed. The increase of the conductive carbon inner shell thickness would lead to an increase in dielectric constant and loss of nanocomposites, while the insulated SiO<sub>2</sub> outer shell exhibited a totally opposite law that the dielectric constant and loss of nanocomposites decrease with increasing SiO<sub>2</sub> outer shell thickness. Numerical simulations were also carried out to theoretically verify the relationship between the dielectric loss and SiO<sub>2</sub> outer shell thickness. This promising controllable multi-shell structure could be extended to a variety of hybrids to develop high-performance dielectric nanocomposites.</p>\",\"PeriodicalId\":36855,\"journal\":{\"name\":\"IET Nanodielectrics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2021-02-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12003\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IET Nanodielectrics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1049/nde2.12003\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IET Nanodielectrics","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1049/nde2.12003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Regulating dielectric performances of Poly(vinylidene fluoride) nanocomposites by individually controlling shell thickness of Core@Double-Shells structured nanowires
The synthesis of core@double-shells structured TiO2@C@SiO2 nanowires (NWs) with variable thickness of carbon inner shell and SiO2 outer shell was achieved by individually controlling the chemical vapour deposition time and amount of silicon precursor added in the sol–gel synthesis. The resultant TiO2@C@SiO2 NWs filled nanocomposites exhibited an excellent dielectric performance with simultaneously improved dielectric constant and suppressed dielectric loss, which could be further regulated by individually controlling the carbon inner shell and SiO2 outer shell thickness. More importantly, the influences of the conductive carbon inner shell and insulated SiO2 outer shell thickness on the dielectric performance of nanocomposites were clearly revealed. The increase of the conductive carbon inner shell thickness would lead to an increase in dielectric constant and loss of nanocomposites, while the insulated SiO2 outer shell exhibited a totally opposite law that the dielectric constant and loss of nanocomposites decrease with increasing SiO2 outer shell thickness. Numerical simulations were also carried out to theoretically verify the relationship between the dielectric loss and SiO2 outer shell thickness. This promising controllable multi-shell structure could be extended to a variety of hybrids to develop high-performance dielectric nanocomposites.