对映选择性氧化还原金催化

IF 2.2 4区工程技术 Q2 Chemistry Gold Bulletin Pub Date : 2022-08-04 DOI:10.1007/s13404-022-00317-9

Chetan C. Chintawar, Nitin T. Patil

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引用次数: 4

摘要

Au(I)/Au(III)氧化还原催化，也称为氧化还原金催化，是近十年来发展起来的一种新技术，为以前金(I)或金(III)催化无法实现的C-C多键的交叉偶联和1,2-失能化反应开辟了可能性。然而，对映选择性Au(I)/Au(III)氧化还原催化直到最近才被发现。Patil和Shi课课组自主开发了新的半可手性(P,N)配体，首次实现了对映选择性氧化还原金催化。图形抽象

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Enantioselective redox gold catalysis

Au(I)/Au(III) redox catalysis, also known as redox gold catalysis, has evolved as a new technique in the past decade, opening up possibilities for the cross-coupling and 1,2-difunctioalization reactions of C–C multiple bonds that were previously inaccessible with gold(I) or gold(III) catalysis. However, the enantioselective Au(I)/Au(III) redox catalysis was missing until recently. The research group of Patil and Shi independently developed new hemilabile chiral (P,N)-ligands to achieve enantioselective redox gold catalysis for the first time.

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来源期刊

Gold Bulletin 工程技术-材料科学：综合

CiteScore

3.30

自引率

4.50%

发文量

审稿时长

3 months

期刊介绍： Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.