用XPS测定了1T ' -MoTe2和2H-MoTe2

IF 1.6 Q3 PHYSICS, CONDENSED MATTER Surface Science Spectra Pub Date : 2021-09-13 DOI:10.1116/6.0001100
J. Shallenberger, Rebecca J. Katz, Z. Mao
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引用次数: 3

摘要

采用化学气相输运法制备了两种不同相的过渡金属二硫化物和二碲化钼(1T′-MoTe2和2H-MoTe2)。在空气中剥落产生无氧表面,然后用x射线光电子能谱分析。获得了两种材料的高分辨率核谱、价谱和俄歇谱,包括Te 3d、Te 4d、Te MNN、Mo 3d和价带谱。先前报道的Te 3d和Mo 3d峰位的差异得到了证实,并且在Te 3d, Te 4d和Mo 3d光谱中记录了金属1T '相的不对称性,这可以证明对识别这些材料的混合物有用。
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1T′-MoTe2 and 2H-MoTe2 by XPS
Two different phases of the transition-metal dichalcogenide and molybdenum ditelluride (1T′-MoTe2 and 2H-MoTe2) were grown by chemical vapor transport. Oxygen-free surfaces were generated by exfoliation in air and then analyzed by x-ray photoelectron spectroscopy. High-resolution core and valence and Auger spectra were acquired for both materials including Te 3d, Te 4d, Te MNN, Mo 3d, and valence band spectra. Differences in Te 3d and Mo 3d peak positions that were previously reported were confirmed, and asymmetry on the metallic 1T′-phase was documented in the Te 3d, Te 4d, and Mo 3d spectra that could prove useful in identifying mixtures of these materials.
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来源期刊
Surface Science Spectra
Surface Science Spectra PHYSICS, CONDENSED MATTER-
CiteScore
1.90
自引率
7.70%
发文量
36
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