绿色合成纳米复合吸附剂在模型油中二苯并噻吩吸附脱硫中的应用

IF 2.1 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Sulfur Chemistry Pub Date : 2023-01-11 DOI:10.1080/17415993.2023.2166349
Hozan Jalal Saleem , Yousif Mustafa Salih , Luqman Omar Hamasalih , Chawan Saiwan Othman
{"title":"绿色合成纳米复合吸附剂在模型油中二苯并噻吩吸附脱硫中的应用","authors":"Hozan Jalal Saleem ,&nbsp;Yousif Mustafa Salih ,&nbsp;Luqman Omar Hamasalih ,&nbsp;Chawan Saiwan Othman","doi":"10.1080/17415993.2023.2166349","DOIUrl":null,"url":null,"abstract":"<div><p>The nanocomposites have an important role in accelerating the adsorption of sulfur compounds because of their improved chemical and mechanical characteristics. In this study, silver nanoparticles, zinc oxide nanoparticles, and silver/zinc oxide nanoparticles were greenly synthesized and loaded with activated carbon by a successive precipitation method for the adsorptive desulfurization of model oil (dibenzothiophene, DBT, in 85% hexane + 15% toluene). The obtained adsorbents were characterized by using UV-visible spectroscopy, Fourier transmission infrared spectroscopy, a field emission scanning electron microscope, energy-dispersive X-ray spectroscopy, X-ray diffraction, and Brunauer-Emmett-Teller surface area (S<sub>BET</sub>) analysis to confirm their structure, chemical composition, functional groups present on the adsorbents, and surface area. The adsorption experiments were conducted under optimal conditions, with 0.15 g of adsorbent dosage and a contact time of 1 h at 25 °C, during which the (Ag/ZnONPS-AC) adsorbent removed 99% of dibenzothiophene (250 mg/l). The total order removal performance of DBT of: Ag/ZnONPS-AC &gt; ZnONPS-AC &gt; AgNPS-AC &gt; AC was observed. Kinetic studies revealed that the adsorption process of (Ag/ZnONPS-AC) obeyed pseudo-second-order kinetics and the Langmuir adsorption isotherm model. This study provides a cost-effective adsorbent for the effective desulfurization of model oil.</p></div>","PeriodicalId":17081,"journal":{"name":"Journal of Sulfur Chemistry","volume":"44 4","pages":"Pages 416-431"},"PeriodicalIF":2.1000,"publicationDate":"2023-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Application of green synthesis nanocomposite adsorbents in the adsorption desulfurization of dibenzothiophene in model oil\",\"authors\":\"Hozan Jalal Saleem ,&nbsp;Yousif Mustafa Salih ,&nbsp;Luqman Omar Hamasalih ,&nbsp;Chawan Saiwan Othman\",\"doi\":\"10.1080/17415993.2023.2166349\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The nanocomposites have an important role in accelerating the adsorption of sulfur compounds because of their improved chemical and mechanical characteristics. In this study, silver nanoparticles, zinc oxide nanoparticles, and silver/zinc oxide nanoparticles were greenly synthesized and loaded with activated carbon by a successive precipitation method for the adsorptive desulfurization of model oil (dibenzothiophene, DBT, in 85% hexane + 15% toluene). The obtained adsorbents were characterized by using UV-visible spectroscopy, Fourier transmission infrared spectroscopy, a field emission scanning electron microscope, energy-dispersive X-ray spectroscopy, X-ray diffraction, and Brunauer-Emmett-Teller surface area (S<sub>BET</sub>) analysis to confirm their structure, chemical composition, functional groups present on the adsorbents, and surface area. The adsorption experiments were conducted under optimal conditions, with 0.15 g of adsorbent dosage and a contact time of 1 h at 25 °C, during which the (Ag/ZnONPS-AC) adsorbent removed 99% of dibenzothiophene (250 mg/l). The total order removal performance of DBT of: Ag/ZnONPS-AC &gt; ZnONPS-AC &gt; AgNPS-AC &gt; AC was observed. Kinetic studies revealed that the adsorption process of (Ag/ZnONPS-AC) obeyed pseudo-second-order kinetics and the Langmuir adsorption isotherm model. This study provides a cost-effective adsorbent for the effective desulfurization of model oil.</p></div>\",\"PeriodicalId\":17081,\"journal\":{\"name\":\"Journal of Sulfur Chemistry\",\"volume\":\"44 4\",\"pages\":\"Pages 416-431\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2023-01-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sulfur Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1741599323000120\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sulfur Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1741599323000120","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1

摘要

纳米复合材料由于其化学和力学特性的改善,在加速含硫化合物的吸附方面具有重要作用。在本研究中,绿色合成了银纳米粒子、氧化锌纳米粒子和银/氧化锌纳米粒子,并通过连续沉淀法负载活性炭,用于模型油(二苯并噻吩,DBT, 85%己烷+ 15%甲苯)的吸附脱硫。采用紫外可见光谱、傅里叶透射红外光谱、场发射扫描电镜、能量色散x射线光谱、x射线衍射和布鲁诺尔-埃米特-泰勒表面积(SBET)分析对所得吸附剂进行了表征,以确定其结构、化学成分、吸附剂上的官能团和表面积。吸附实验在最佳条件下进行,吸附剂用量为0.15 g,接触时间为1 h,在25℃条件下,(Ag/ZnONPS-AC)吸附剂对二苯并噻吩(250 mg/l)的去除率为99%。观察了Ag/ZnONPS-AC > ZnONPS-AC > AgNPS-AC > AC DBT的总脱序性能。动力学研究表明,(Ag/ZnONPS-AC)的吸附过程符合拟二级动力学和Langmuir吸附等温模型。该研究为模型油的有效脱硫提供了一种经济高效的吸附剂。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Application of green synthesis nanocomposite adsorbents in the adsorption desulfurization of dibenzothiophene in model oil

The nanocomposites have an important role in accelerating the adsorption of sulfur compounds because of their improved chemical and mechanical characteristics. In this study, silver nanoparticles, zinc oxide nanoparticles, and silver/zinc oxide nanoparticles were greenly synthesized and loaded with activated carbon by a successive precipitation method for the adsorptive desulfurization of model oil (dibenzothiophene, DBT, in 85% hexane + 15% toluene). The obtained adsorbents were characterized by using UV-visible spectroscopy, Fourier transmission infrared spectroscopy, a field emission scanning electron microscope, energy-dispersive X-ray spectroscopy, X-ray diffraction, and Brunauer-Emmett-Teller surface area (SBET) analysis to confirm their structure, chemical composition, functional groups present on the adsorbents, and surface area. The adsorption experiments were conducted under optimal conditions, with 0.15 g of adsorbent dosage and a contact time of 1 h at 25 °C, during which the (Ag/ZnONPS-AC) adsorbent removed 99% of dibenzothiophene (250 mg/l). The total order removal performance of DBT of: Ag/ZnONPS-AC > ZnONPS-AC > AgNPS-AC > AC was observed. Kinetic studies revealed that the adsorption process of (Ag/ZnONPS-AC) obeyed pseudo-second-order kinetics and the Langmuir adsorption isotherm model. This study provides a cost-effective adsorbent for the effective desulfurization of model oil.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Sulfur Chemistry
Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.10
自引率
9.10%
发文量
38
审稿时长
6-12 weeks
期刊介绍: The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.
期刊最新文献
A green and efficient synthesis of alkyl 2-((5-hydroxy-1H-pyrazole-4-carbonothioyl)thio)acetates via a one-pot, solvent-free reaction Synthesis of novel isoxazole/dihydroisoxazole tethered β-lactam hybrids via regiospecific 1,3-dipolar cycloaddition methodology on 3-phenylthio-β-lactams Thiazole derivatives: prospectives and biological applications Synthesis of benzothioamide derivatives from benzonitriles and H2S-based salts in supercritical CO2 Synthesis and biological evaluation of 2-(2-hydrazinyl) thiazole derivatives with potential antibacterial and antioxidant activity
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1