用XPS蚀刻法测定纯Mg在Cl−环境中的腐蚀产物膜

IF 2.7 4区 材料科学 Q3 ELECTROCHEMISTRY Corrosion Reviews Pub Date : 2023-08-15 DOI:10.1515/corrrev-2023-0064
Lin Sun, Deqing Ma, Ye Liu, Q. Qin, Liang Liang, Hongbin Ma, Fuan Wei, Chao Zhang
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引用次数: 0

摘要

摘要采用X射线光电子能谱(XPS)和氩离子刻蚀相结合的方法分析了纯镁在3.5 % 10的NaCl溶液 min.试样表面的XPS光谱表明,腐蚀产物主要由Mg(OH)2和Mg2Cl(OH)3·xH2O组成。Mg2Cl(OH)3的形成过程是Mg(OH)2与Cl−和H+在弱酸性溶液中的反应。XPS结果表明,随着刻蚀时间的增加,Mg2Cl(OH)3·xH2O的强度从0 s到4680 s。证实了当Cl−攻击Mg(OH)2膜时,Mg(OH2)2的边缘向外突出,然后分裂成Mg2Cl(OH)3,因此Mg2Cl。同时,将扫描电子显微镜(SEM)和透射电子显微镜(TEM)与XPS相结合,分析了腐蚀机理。此外,结果表明,XPS与Ar离子刻蚀相结合是一种很好的表征腐蚀产物反应的方法。
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Determination of corrosion product film on pure Mg in Cl− environment using XPS etching
Abstract X-ray photoelectron spectroscopy (XPS) combined with Ar ion etching was used to analyse the surface film of pure Mg at different depth after immersion in 3.5 % NaCl solution for 10 min. The XPS spectra of specimen surface showed that the corrosion products are mainly made up of Mg(OH)2 and Mg2Cl(OH)3·xH2O. The formation process of Mg2Cl(OH)3 is the reaction of Mg(OH)2 and Cl− and H+ in weak acidic solutions. The XPS results indicated that the intensities of Mg2Cl(OH)3·xH2O decreased with the increase of etching time from 0 s to 4680 s. It is confirmed that the edge of Mg(OH)2 protrudes outward and then splits into Mg2Cl(OH)3 when Cl− attacks the Mg(OH)2 films, so the Mg2Cl(OH)3 attached to Mg(OH)2. Meanwhile, coupling the scanning electron microscope (SEM) and transmission electron microscopy (TEM) with the XPS to analyze the corrosion mechanism. Furthermore, the results displayed that the XPS combined with Ar ion etching is a good characterization method to understand the reaction of corrosion products.
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来源期刊
Corrosion Reviews
Corrosion Reviews 工程技术-材料科学:膜
CiteScore
5.20
自引率
3.10%
发文量
44
审稿时长
4.5 months
期刊介绍: Corrosion Reviews is an international bimonthly journal devoted to critical reviews and, to a lesser extent, outstanding original articles that are key to advancing the understanding and application of corrosion science and engineering in the service of society. Papers may be of a theoretical, experimental or practical nature, provided that they make a significant contribution to knowledge in the field.
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