{"title":"罗丹明6G染料在Al-MCM-41和MCM-41介孔材料上的吸附","authors":"Houda Douba, O. Mohammedi, B. Cheknane","doi":"10.15255/kui.2022.001","DOIUrl":null,"url":null,"abstract":"The present study aimed to evaluate the potential of mesoporous silica MCM-41 and Al-MCM-41 (molar ratio Si/Al = 20) for the removal of Rhodamine 6G (Rh6G) from aqueous solution. The adsorbents were characterised by XRD, FTIR, SEM-EDX, BET, and UV-Raman. Obtained results related to XRD analysis indicated that the MCM-41 structure remained intact after the incorporation of Al species. Kinetic adsorption study showed that the higher removal (88.75 %, 26.62 mg g −1 ) of Rh6G dye was achieved by Al-MCM-41 at 60 min. FTIR analysis showed that hydrogen bonding played the dominant role in the Rh6G removal mechanism, while the pH results showed that electrostatic interaction was also a key factor. This study shows that the prepared mesoporous materials are inexpensive and efficient adsorbents for the removal of cationic dyes.","PeriodicalId":43849,"journal":{"name":"Kemija u Industriji-Journal of Chemists and Chemical Engineers","volume":" ","pages":""},"PeriodicalIF":0.6000,"publicationDate":"2022-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Adsorption of Rhodamine 6G Dye onto Al-MCM-41 and MCM-41 Mesoporous Materials\",\"authors\":\"Houda Douba, O. Mohammedi, B. Cheknane\",\"doi\":\"10.15255/kui.2022.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present study aimed to evaluate the potential of mesoporous silica MCM-41 and Al-MCM-41 (molar ratio Si/Al = 20) for the removal of Rhodamine 6G (Rh6G) from aqueous solution. The adsorbents were characterised by XRD, FTIR, SEM-EDX, BET, and UV-Raman. Obtained results related to XRD analysis indicated that the MCM-41 structure remained intact after the incorporation of Al species. Kinetic adsorption study showed that the higher removal (88.75 %, 26.62 mg g −1 ) of Rh6G dye was achieved by Al-MCM-41 at 60 min. FTIR analysis showed that hydrogen bonding played the dominant role in the Rh6G removal mechanism, while the pH results showed that electrostatic interaction was also a key factor. This study shows that the prepared mesoporous materials are inexpensive and efficient adsorbents for the removal of cationic dyes.\",\"PeriodicalId\":43849,\"journal\":{\"name\":\"Kemija u Industriji-Journal of Chemists and Chemical Engineers\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2022-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Kemija u Industriji-Journal of Chemists and Chemical Engineers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15255/kui.2022.001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kemija u Industriji-Journal of Chemists and Chemical Engineers","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15255/kui.2022.001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Adsorption of Rhodamine 6G Dye onto Al-MCM-41 and MCM-41 Mesoporous Materials
The present study aimed to evaluate the potential of mesoporous silica MCM-41 and Al-MCM-41 (molar ratio Si/Al = 20) for the removal of Rhodamine 6G (Rh6G) from aqueous solution. The adsorbents were characterised by XRD, FTIR, SEM-EDX, BET, and UV-Raman. Obtained results related to XRD analysis indicated that the MCM-41 structure remained intact after the incorporation of Al species. Kinetic adsorption study showed that the higher removal (88.75 %, 26.62 mg g −1 ) of Rh6G dye was achieved by Al-MCM-41 at 60 min. FTIR analysis showed that hydrogen bonding played the dominant role in the Rh6G removal mechanism, while the pH results showed that electrostatic interaction was also a key factor. This study shows that the prepared mesoporous materials are inexpensive and efficient adsorbents for the removal of cationic dyes.
期刊介绍：
Kemija u industriji (Chemistry in industry) is monthly journal which is being published already for almost 60 years continually and from very beginning it is a journal of chemists and chemical engineers. It is official journal of Croatian Society of Chemists and Engineers and of Croatian Chemical Society. It is edited by Croatian Society of Chemists and Engineers.
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