S. Korniy, I. Zin, O. Khlopyk, M. Holovchuk, M. Danyliak, B. Datsko, P. Lyutyy
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Aluminium alloy corrosion inhibition by a two-stage modified nanoporous zeolite
ABSTRACT A two-stage synthesis of anti-corrosion pigments based on synthetic zeolites was performed. New pigments retain the zeolite framework structure in the nanopores of which the amorphised phosphate phase is formed. The pigments effectively reduce the aluminium alloy corrosion in sodium chloride solution. The most effective pigment is obtained by mechanochemical modification of zeolite with calcium cations, followed by liquid-phase treatment with zinc nitrate and sodium phosphate. The pigments induce the formation of a protective film of zinc hydroxides on intermetallic inclusions of the alloy. The formation of phosphates is possible on the anode sections. The pigments can become promising inhibitory components of primer paints used for the protection of structures made from aluminium alloys.
期刊介绍:
Corrosion Engineering, Science and Technology provides broad international coverage of research and practice in corrosion processes and corrosion control. Peer-reviewed contributions address all aspects of corrosion engineering and corrosion science; there is strong emphasis on effective design and materials selection to combat corrosion and the journal carries failure case studies to further knowledge in these areas.