废弃咖啡上的绿色生物复合材料

Pub Date : 2023-03-18 DOI:10.15255/kui.2022.079
Ema Čemerika, Dora Milički, M. Miloloža, Dajana Kučić Grgić, Krunoslav Žižek, Vesna Ocelić Bulatović
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引用次数: 0

摘要

咖啡市场的持续增长产生了大量的废咖啡渣(SCG),占咖啡消费后废物的95%。SCG包含大量不同的资源,只需要将其转换为另一种可用形式。另一方面,当今世界上几乎所有行业中塑料废物的过度生产正在造成严重的环境污染,导致生物可降解聚合物和生物复合材料的使用增加。正是由于绿色聚乳酸(SCG)的含量巨大,而聚乳酸(PLA)的生物降解性较慢,本研究旨在通过将不同比例的聚乳酸与绿色聚乳酸混合制备绿色聚乳酸与SCG生物复合材料,研究其性能和生物降解性。采用差示扫描量热法和热重分析法研究了生物复合材料的热性能。采用激光衍射法研究了SCG的粒径分布及吸水率。通过19 d的堆肥过程对生物复合材料进行生物降解。热性能测试结果表明,SCG作为填料不影响PLA基体的相变,但会降低PLA_SCG生物复合材料的热稳定性。吸水试验结果表明,由于填料的亲水性,SCG用量的增加导致生物复合材料吸水率的增加。在光镜下,SCG含量较低的生物复合材料中微生物的表面攻击可见,而SCG填料含量较高的生物复合材料中微生物的渗透更深。
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Zeleni biokompoziti na bazi otpada taloga kave
The continuous growth of the coffee market generates enormous amounts of spent coffee grounds (SCG), which account for up to 95 % of waste after coffee consumption. SCG contain a wealth of different resources that just need to be converted into another usable form. On the other hand, to - day’s excessive production of plastic waste in almost all industries worldwide is causing significant environmental pollution, leading to increased use of biodegradable polymers and biocomposites. Precisely because of the enormous amounts of SCG and the slow biodegradability of polylac - tide (PLA), this study aimed to investigate the properties and biodegradability of biocomposites made from green PLA and SCG, which were prepared by mixing the PLA matrix with different proportions of SCG. The thermal properties of the biocomposite were investigated by differential scanning calorimetry and thermogravimetric analysis. The particle size distribution of the SCG was studied by laser diffraction method, as well as the water absorption. The biodegradation of the biocomposite was carried out by a composting process of 19 days. The results of the thermal properties test showed that the SCG as filler did not affect the phase transitions of the PLA matrix, but it did affect the reduction of the thermal stability of the PLA_SCG biocomposite. The results of the water absorption test showed that increasing the amount of SCG leads to an increase in water absorption in biocomposites, due to the hydrophilic nature of the filler. On the light micro - scopic images, the surface attack of microorganisms was visible in biocomposites with lower SCG content, while deeper penetration was observed in biocomposites with higher SCG filler content.
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