利用固定床催化装置提高慢速热解产气率

Ahmed Zahra, M. El-Wahab, M. Tawfik
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引用次数: 1

摘要

与复杂而昂贵的快速热解技术相比,使用固定床热解器的生物质慢速热解是一种简单而廉价的技术,可用于小型农场。然而,慢速热解初级产物产生生物炭,生物油和热解气体的产率较低。因此,由于生物炭具有在农场广泛应用的优势,迫切需要在缓慢热解条件下提高热解气体的产量。因此,本工作旨在制造和运行一个小型固定床热解器,以在缓慢热解条件下(加热速率为0.01-1℃/s,蒸汽停留时间为4分钟)和完全缺氧的情况下,提高芒果树修剪原木碎片的热解气体生产率。研究了在不同的最终热解温度(300350和400°C,颗粒长度范围为1-5、10-15和20-25mm)下热解气体的产生。结果表明,热解温度从300-400°C升高,地面MPL长度从20-25mm减小,热解气体浓度、产气量、,较高的热解气体热值(HHVg)和能量转换效率分别提高了约34.28%、61.15%、12.68%和66.10%,以及高浓度的可燃气体(例如H2、CH4)。此外,热解气体的每能量单位的最佳成本(0.085 EGP/MJ或0.005$/MJ)分别比天然气和液化石油气的每能量单元的成本低约11.45%和75.07%。
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ENHANCING THE PYROLYTIC GAS PRODUCTION GENERATED BY SLOW PYROLYSIS USING A FIXED-BED PROLYZER
The biomass slow pyrolysis using the fixed-bed pyrolyzer is a simple and inexpensive technique that can be used in small farms comparing to the complex and expensive technology of the fast pyrolysis. However, slow pyrolysis primary produces bio-char and lower yields of bio-oil and pyrolytic gas. Thus, there is urgent need to enhance pyrolytic gas production under the slow pyrolysis conditions on the account of bio-char due to the advantage of using the gas in wide applications in farm. Hence, this work aims to fabricate and operate a small-scale fixed bed pyrolyzer to enhance the pyrolytic gas productivity from the ground pieces of Mango trees Pruning Logs (MPLs) under slow pyrolysis conditions (heating rate of 0.01-1 oC/s, vapor residence time of 4 min.) and full absence of oxygen. The pyrolytic gas production was investigated under different final pyrolysis temperatures of 300,350 and 400°C, particle length ranges of 1-5, 10-15 and 20-25 mm. The obtained results revealed that, the increase of pyrolysis temperature from 300-400°C and decrease of the ground MPL length from 20-25 to 1-5 mm was accompained with explicit increment in the pyrolytic gas concentration, gas yield, higher heating value of pyrolytic gas (HHVg) and energy conversion efficiency by about 34.28%, 61.15%, 12.68% and 66.10%, respectively along to high concentrations of the combustible gases )e.i. H2, CH4). Additionally, the optimal cost per energy unit of pyrolytic gas (0.085 EGP/MJ or 0.005 $/MJ) is lower than cost per energy unit of the natural gas and LPG by about 11.45% and 75.07%, respectively.
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