废食用油制备生物柴油的特性研究

Mai Kurdi, M. Sitohy, H. Hefnawy, A. Gomaa
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引用次数: 0

摘要

能源消耗的增加和石油储量的枯竭推高了全球油价。石油储量的减少是另一个全球风险因素。通过酯交换反应生产生物柴油植物油和动物脂肪是一种相当可观的能源替代品。本研究以废食用油为原料,以HCl为催化剂,采用甲醇酯交换法制备生物柴油。生物柴油的生产首先是将生的和收集的废食用油混合到一个池子里。将混合物在室温下沉淀8小时,然后通过HCl(油重量的1%)与甲醇混合,在甲醇:油比为1:4的情况下,在90℃开始酯交换过程。该过程在冷凝器下持续9小时。生物柴油的纯化是通过用热水(温度70°C)洗涤产品两次,以去除过量的反应物和副产品,如酒精、催化剂、肥皂、甘油和脂肪酸甲酯(FAME)。由此产生的柴油密度为3.72 kg/m(在15℃时),运动粘度为8.93 mm/秒。,在40℃下,废油的发热量为41299 kj/kg,总酸值为0.111,十六烷值为48.95,酸值(AV)为1.135 mg/koh,酯值(EV)为178.42 mg/koh。皂化值(SV)为179.56 mg/koh, pH为5.7,甘油质量为97.53 (Gw)。
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CHARACTERIZATION OF BIODIESEL PREPARED FROM WASTE COOKING OIL
Increased energy consumption and the depletion of petroleum reserves have pushed up oil prices globally. Diminishing the petroleum reserve is another global risk factor. Producing Biodiesel vegetable oils and animal fat by transesterification can be a considerable energy alternative. In this study, biodiesel is produced from waste cooking oil by transesterification method with methanol in the presence of HCl as a catalyst. Biodiesel production begins with mixing raw the collected used cooking oil into one pool. The mixture is then settled for 8 hours at room temperature before initiating the transesterification process 90 o C by mixing HCl (1% of oil weight) with methanol, while the methanol: oil ratio is 1:4. The process lasts for 9 h under a condenser. Biodiesel purification is carried out by washing the product twice with hot water (temperature 70°C) to remove excess reactants and byproducts such as alcohol, catalysts, soap and glycerine, and fatty acid methyl ester (FAME). The resulting diesel density of 3.72 kg/m (at 15oC), a kinematic viscosity of 8.93 mm/sec., at 40oC, calorific value was 41299 kj/kg, Total acid number of 0.111 was for waste cooking oil, Cetane number of 48.95, acid value (AV) was 1.135 mg/koh was and Ester value (EV) was 178.42 mg/koh. The Saponification value (SV) was 179.56 mg/koh, pH was 5.7, and Glycerol Weight was 97.53 (Gw).
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