Bo Xing, Chaoting Fu, G. Yang, X. Song, Xingyong Liu, Xiaonan Liu, Qiang Zhou, Zhongcai Pan, J. You, Yuling Ye
{"title":"Na2S2O8在醋汁衍生的N,S共掺杂介孔碳上的氧化降解水溶液中的磺胺二甲嘧啶","authors":"Bo Xing, Chaoting Fu, G. Yang, X. Song, Xingyong Liu, Xiaonan Liu, Qiang Zhou, Zhongcai Pan, J. You, Yuling Ye","doi":"10.1111/wej.12838","DOIUrl":null,"url":null,"abstract":"N,S‐codoped mesoporous carbon (S/NMC) as an effective catalyst toward the catalytic persulfate oxidation of sulfamethazine (SMZ) was fabricated conveniently using vinasse as the C/N source, Na2S as the S precursor and nano‐SiO2 as the template, respectively. The effect of S precursor dosage on the textural properties and surface chemistry of S/NMCs were characterized by N2 adsorption/desorption, Raman spectra, X‐ray diffractometer (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT‐IR) and X‐ray photoelectron spectroscopy (XPS). It was found that more S precursor dosage presented an enhanced SMZ degradation performance due to the significant role of more S precursor dosage: (i) larger specific surface area and (ii) more active surface groups including pyridine N, graphite N, quinone‐like O and thiophene‐like S. In addition, quenching experiments showed that free radical and nonradical oxidation processes are the main processes of SMZ degradation. The findings provided a new idea for the resource utilization of vinasse and the development of catalytic persulfate oxidation of organic pollution.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":"37 1","pages":"316 - 325"},"PeriodicalIF":1.7000,"publicationDate":"2022-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Oxidative degradation of sulfamethazine in aqueous solution by the activation of Na2S2O8 over vinasse‐derived N,S‐codoped mesoporous carbon\",\"authors\":\"Bo Xing, Chaoting Fu, G. Yang, X. Song, Xingyong Liu, Xiaonan Liu, Qiang Zhou, Zhongcai Pan, J. You, Yuling Ye\",\"doi\":\"10.1111/wej.12838\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"N,S‐codoped mesoporous carbon (S/NMC) as an effective catalyst toward the catalytic persulfate oxidation of sulfamethazine (SMZ) was fabricated conveniently using vinasse as the C/N source, Na2S as the S precursor and nano‐SiO2 as the template, respectively. The effect of S precursor dosage on the textural properties and surface chemistry of S/NMCs were characterized by N2 adsorption/desorption, Raman spectra, X‐ray diffractometer (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT‐IR) and X‐ray photoelectron spectroscopy (XPS). It was found that more S precursor dosage presented an enhanced SMZ degradation performance due to the significant role of more S precursor dosage: (i) larger specific surface area and (ii) more active surface groups including pyridine N, graphite N, quinone‐like O and thiophene‐like S. In addition, quenching experiments showed that free radical and nonradical oxidation processes are the main processes of SMZ degradation. The findings provided a new idea for the resource utilization of vinasse and the development of catalytic persulfate oxidation of organic pollution.\",\"PeriodicalId\":23753,\"journal\":{\"name\":\"Water and Environment Journal\",\"volume\":\"37 1\",\"pages\":\"316 - 325\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2022-12-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water and Environment Journal\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1111/wej.12838\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water and Environment Journal","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1111/wej.12838","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Oxidative degradation of sulfamethazine in aqueous solution by the activation of Na2S2O8 over vinasse‐derived N,S‐codoped mesoporous carbon
N,S‐codoped mesoporous carbon (S/NMC) as an effective catalyst toward the catalytic persulfate oxidation of sulfamethazine (SMZ) was fabricated conveniently using vinasse as the C/N source, Na2S as the S precursor and nano‐SiO2 as the template, respectively. The effect of S precursor dosage on the textural properties and surface chemistry of S/NMCs were characterized by N2 adsorption/desorption, Raman spectra, X‐ray diffractometer (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT‐IR) and X‐ray photoelectron spectroscopy (XPS). It was found that more S precursor dosage presented an enhanced SMZ degradation performance due to the significant role of more S precursor dosage: (i) larger specific surface area and (ii) more active surface groups including pyridine N, graphite N, quinone‐like O and thiophene‐like S. In addition, quenching experiments showed that free radical and nonradical oxidation processes are the main processes of SMZ degradation. The findings provided a new idea for the resource utilization of vinasse and the development of catalytic persulfate oxidation of organic pollution.
期刊介绍:
Water and Environment Journal is an internationally recognised peer reviewed Journal for the dissemination of innovations and solutions focussed on enhancing water management best practice. Water and Environment Journal is available to over 12,000 institutions with a further 7,000 copies physically distributed to the Chartered Institution of Water and Environmental Management (CIWEM) membership, comprised of environment sector professionals based across the value chain (utilities, consultancy, technology suppliers, regulators, government and NGOs). As such, the journal provides a conduit between academics and practitioners. We therefore particularly encourage contributions focussed at the interface between academia and industry, which deliver industrially impactful applied research underpinned by scientific evidence. We are keen to attract papers on a broad range of subjects including:
-Water and wastewater treatment for agricultural, municipal and industrial applications
-Sludge treatment including processing, storage and management
-Water recycling
-Urban and stormwater management
-Integrated water management strategies
-Water infrastructure and distribution
-Climate change mitigation including management of impacts on agriculture, urban areas and infrastructure