空果束生物炭吸附硫化氢的动力学模型

A. Alias, D. Qarizada, A. Ariffin, N. Noraini, Z. A. Rashid
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引用次数: 0

摘要

本研究旨在研究吸附动力学模型的详细状态,并研究空果串水凝胶(EFB)对硫化氢的吸附应用、动力学参数的确定以及模型之间的比较,以选择最佳拟合模型。所使用的动力学模型是伪一阶和伪二阶模型。相关系数用于评估方程R2的适用性。在获得结果之后,通过比较每个模型的R2来进行比较。伪二阶模型具有较高的相关系数R2,使其成为最适合吸附系统的动力学模型。伪一阶对干床高度影响的R2为0.8814,而其对粉床高度的影响为0.9537,对湿床高度的作用为0.9607。同时,伪二阶对干床高度影响的R2为0.89,对粉床高度影响为0.99,对湿床高度影响是0.99,在动力学模型中最高。基于这些结果,拟二阶模型最好地描述了水凝胶生物炭对硫化氢(H2S)的吸附。所使用的动力学模型是源自空果串(EFB)的水凝胶吸附硫化氢的伪一阶和伪二阶模型。基于这些结果,拟二阶模型最好地描述了水凝胶生物炭对硫化氢(H2S)的吸附。动力学研究对于理解反应和工艺设计非常重要。这篇文章的真实性结果被发现有17%的相似性。本文的新颖之处在于对基于EFB开发的新型吸附剂吸附H2S的动力学研究。
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Kinetics models of hydrogen sulphide adsorption from hydrogel biochar derived from empty fruit bunch (EFB)
This research aims to investigate the detailed state of adsorption kinetics modelling and research on the application of hydrogen sulfide adsorption by hydrogel derived from empty fruit bunch (EFB), the determination of the kinetics parameters, and the comparison between models in a selection of the best-fit model.The kinetics modelling used are pseudo-first-order and pseudo-second-order models. The correlation coefficient was used to evaluate the suitability of the equation R2. After obtaining the results, the comparison was made by comparing the R2 of each model. The pseudo-second-order model has a higher value of correlation coefficient, R2, making it the most suitable kinetics model for adsorption systems.The R2 for pseudo-first-order on the effect of dry bed height was 0.8814, whereas its effect on powder bed height was 0.9537, and that of the wet bed height was 0.9607. Meanwhile, the R2 for pseudo-second-order on the effect of dry bed height was 0.89, on the effect of the powder bed height was 0.99, and on the effect of the bed height of wet was 0.99, the highest among kinetic models. Based on the results, the pseudo-second-order model best describes the adsorption of hydrogen sulfide (H2S) by hydrogel biochar.The kinetics modelling used are pseudo-first-order, and pseudo-second-order models for hydrogen sulfide adsorption by hydrogel originating from empty fruit bunches (EFB).Based on the results, the pseudo-second-order model best describes the adsorption of hydrogen sulfide (H2S) by hydrogel biochar. Kinetic studies are important in understanding the reactions and design of the process.The authenticity results of this article were found to be 17% similar. The novelty of this paper is the kinetics study of the new adsorbent developed based on EFB to adsorb H2S.
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来源期刊
Archives of materials science and engineering
Archives of materials science and engineering Materials Science-Materials Science (all)
CiteScore
2.90
自引率
0.00%
发文量
15
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