1,4-丁二醇+甲酚二元混合物在不同温度下的粘度特性

IF 1.4 Q3 CHEMISTRY, MULTIDISCIPLINARY Physical Chemistry Research Pub Date : 2021-12-01 DOI:10.22036/PCR.2021.270810.1880

N. Kolla, SRINIVASs Jaddu, Kavitha Ch, R. Dey

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引用次数: 0

摘要

测定了1，4-丁二醇与邻甲酚、间甲酚和对甲酚的二元混合物在303.15308.15313.15K和318.15K下的粘度。粘度的偏差，, 和过剩的吉布斯活化能(G*E）的结构变化和相互作用。将偏差/超额值拟合到Redlich-Kister方程中，以确定拟合参数和均方根偏差。二元混合物粘度的结果用于测试Bingham、Frenkel、Kendall、HindUbbelhode、Refutas、Sutherland Wassiljiewa、Gambill、McAllister、Hind、Grunberg、Wijk、McAllister4 body、Tamura Kurata、Katti Chaudhri和Nhaesi的半经验关系。

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Viscometric Properties of Binary Mixtures of 1,4-Butanediol + Cresols at Different Temperatures

The viscosities of binary mixtures of 1,4-butanediol with o-cresol, m-cresol and p-cresol have been determined at 303.15, 308.15, 313.15 and 318.15 K over the entire mole fraction range. The deviation in viscosity,, and excess Gibbs energy of activation (G*E) of viscous flow have been examined in terms of structural changes and interactions. The deviations/excess values were fitted to the Redlich-Kister equation to determine the fitting parameters and the root-mean square deviations. The results obtained for viscosity of binary mixtures were used to test the semi-empirical relations of Bingham, Frenkel, Kendall, HindUbbelhode, Refutas, Sutherland Wassiljiewa, Gambill, McAllister, Hind, Grunberg, Wijk, McAllister 4 body, Tamura Kurata, Katti-Chaudhri and Nhaesi.

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来源期刊

Physical Chemistry Research CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.70

自引率

8.30%

发文量

期刊介绍： The motivation for this new journal is the tremendous increasing of useful articles in the field of Physical Chemistry and the related subjects in recent years, and the need of communication between Physical Chemists, Physicists and Biophysicists. We attempt to establish this fruitful communication and quick publication. High quality original papers in English dealing with experimental, theoretical and applied research related to physics and chemistry are welcomed. This journal accepts your report for publication as a regular article, review, and Letter. Review articles discussing specific areas of physical chemistry of current chemical or physical importance are also published. Subjects of Interest: Thermodynamics, Statistical Mechanics, Statistical Thermodynamics, Molecular Spectroscopy, Quantum Chemistry, Computational Chemistry, Physical Chemistry of Life Sciences, Surface Chemistry, Catalysis, Physical Chemistry of Electrochemistry, Kinetics, Nanochemistry and Nanophysics, Liquid Crystals, Ionic Liquid, Photochemistry, Experimental article of Physical chemistry. Mathematical Chemistry.