新型高分子右旋糖酐在12MHz水介质中的超声研究

IF 0.9 Q4 CHEMISTRY, MULTIDISCIPLINARY Current Microwave Chemistry Pub Date : 2023-08-10 DOI:10.2174/2213335610666230810094605
Subhraraj Panda
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引用次数: 0

摘要

物质的特性和分子过程的动力学通过声学方法进行了研究。分子声学的主要技术是测量声速和吸声,以及这些量与不同物理变量(包括压力、温度和波频率)之间的关系。分子声学在20世纪30年代作为一个独立的领域出现。然而,当人们发现许多物质在声波传播过程中会分散声速,而经典定律规定吸收系数与频率的平方成正比时,它并不能充分描述声音是如何被吸收的。之所以采用超声波技术,是因为它是最流行的技术之一,使用起来非常容易,并且可以提供精确的速度结果。通过对结果的仔细分析,发现了溶质和溶剂之间的相关性。在制药、农业和化妆品行业,葡聚糖及其从一些精选菌株中提取的衍生物有着广泛的用途。这就是为什么我们选择它进行研究。为了评估温度和浓度对含有聚合物右旋糖酐的水性介质的影响,超声性质是至关重要的。分别使用比重瓶、奥斯特瓦尔德粘度计和超声波干涉仪测量密度(ρ)、粘度(η)、,以及在“303 K、308 K、313 K、318 K和323 K”下的超声速度(u)。实验参数用于确定声学参数“绝热压缩性、分子间自由长度、弛豫时间、声阻抗和吉布自由能”。使用比重瓶、奥斯特瓦尔德粘度计测量溶液的密度、粘度和超声速度,以及超声波干涉仪,并基于测量的参数来计算热声参数。使用超声波检查右旋糖酐水溶液的物理化学行为的应用包括理解分子相互作用的性质。研究了浓度和温度对右旋糖酐水溶液热声特性的影响。氢键、电荷转移络合物以及氢键和络合物的溶解只是分子之间存在的力以及分析如何解释其性质的几个例子。存在微弱的分子间作用力。超声波技术的最新发展使其成为评估液体分子物理和化学行为信息的有效工具。
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Ultrasonic study of novel polymer dextran in aqueous media at 12 MHz
The characteristics of matter and the dynamics of molecular processes are examined by acoustic approaches. The primary techniques in molecular acoustics are the measurement of sound speed and sound absorption, as well as the relationship between these quantities and different physical variables including pressure, temperature, and wave frequency. Molecular acoustics emerged as a separate field in the 1930s. When it was discovered that many substances disperse the speed of sound during the transmission of sound waves through them and that the classical law, which states that the coefficient of absorption is proportional to the square of the frequency, however, it does not adequately describe how sound is absorbed. The ultrasonic technique is employed because it is one of the most popular techniques, which is very easy to use, and provides precise velocity results. With careful analysis of the results, the correlation between solute and solvent was discovered. In the pharmaceutical, agricultural, and cosmetics industries, dextran and its derivatives from a few select strains have found a wide range of uses. This is why we have chosen it for our study. For assessing the impact of temperature and concentration on the aqueous medium containing the polymer dextran, ultrasonic properties are crucial. Pycnometer, Ostwald viscometer, and ultrasonic interferometer were used respectively to measure density (ρ), viscosity (η), and ultrasonic speed (u) at "303 K, 308 K, 313 K, 318 K, and 323 K." The experimental parameters are used to determine the acoustic parameters "adiabatic compressibility, Intermolecular free length, relaxation time, acoustic impedance, and Gibb's free energy". To measure the density, viscosity, and ultrasonic velocity of the solution using a pycnometer, an Ostwald's viscometer, and an ultrasonic interferometer, and to calculate the thermo acoustical parameters based on the measured parameters. Applications for examining the physico-chemical behaviour of aqueous dextran using ultrasound include understanding the nature of molecular interactions. It was investigated how concentration and temperature affected the thermoacoustic characteristics of aqueous dextran. Hydrogen bonds, charge transfer complexes, and the dissolution of hydrogen bonds and complexes are only a few examples of the forces that exist between molecules and how the analysis has interpreted their nature. Weak intermolecular forces exist. Recent developments in ultrasonic techniques have made them an effective tool for evaluating information regarding the physical and chemical behaviour of liquid molecules.
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Current Microwave Chemistry
Current Microwave Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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