天然橡胶复合材料二元加速器系统的性能

I. N. Indrajati, I. R. Dewi
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引用次数: 3

摘要

加速器系统对橡胶化合物提供不同的响应,进而影响其最终性能。促进剂,如2,2'-二硫代双(苯并噻唑)(MBTS)、N-环己基苯并噻唑-2-硫酰胺(CBS)和二苯胍(DPG)已被选择用于研究。评价了不同配比的MBTS/DPG和CBS/DPG对天然橡胶(NR)复合材料的反应。典型地使用穆尼粘度计和移动模流变仪(MDR)分析了化合物的流变性能和固化特性。结果表明,DPG在体系中的加入增加了化合物的粘度,并影响了该过程中的分子量。此外,DPG的添加还通过减少焦烧时间(ts2)和减少固化时间(t90)来缩短诱导期。由于弹性元件的强支配作用,二元配对加速器的流动特性较差。通常,基于CBS的系统比基于MBTS的系统提供了更多的平衡特性。
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Performance of binary accelarator system on natural rubber compound
Accelerator system provides different response onto the rubber compound, and in turn influences its final properties. Accelerators, such as 2,2'-Dithiobis (benzothiazole) (MBTS), N-Cyclohexylbenzothiazole-2-Sulfenamide (CBS) and diphenyl guanidine (DPG), has been selected for the study. Response of paired accelerator, MBTS/DPG and CBS/DPG in various ratio, on natural rubber (NR) compound was evaluated. Rheological properties and cure characteristics of the compounds were analyzed using Mooney viscometer and moving die rheometer (MDR) typically. Results findings showed that incorporation of DPG into the system has increased the viscosity of the compound and effected the molecular weight during the process. Further, the addition of DPG also shortened the induction period by reducing the scorch time (ts2) and decreasing the cure time (t90). Binary paired accelerator resulted in poor flow characteristic as a result of strong domination of elastic element. In general, the CBS-based system provided more balance characteristic than those of MBTS-based.
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