功能化二硫代氨基甲酸镍配合物的合成、光谱表征、生物活性和导电性能及溶剂萃取研究

IF 2.1 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Sulfur Chemistry Pub Date : 2023-06-01 DOI:10.1080/17415993.2022.2157680
Vinay Kumar Maurya , Lal Bahadur Prasad , Anupam Singh , Kunal Shiv , Akhilesh Prasad
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引用次数: 2

摘要

一系列新的通式[ML2]的二硫代氨基甲酸镍(II)配合物,(其中L = 合成了(4-氟苄基)氨基甲二硫代苄基酯(L1)、(4-氰基苄基)氨基乙二硫代苄酯(L2,质谱和热重分析(TGA)。采用连续变化法(Job's法)测定配合物的化学计量。用TGA分析了金属配合物在氮气氛中的热分解行为。作为热分解过程的结果,所有的配合物都产生了作为最终产物的NiS。X射线衍射(XRD)、能量色散X射线分析(EDAX)和透射电子显微镜(TEM)研究证实了NiS纳米材料的形成。NiS的结晶尺寸在19.97至21.35之间  nm范围内。固态电导率表明,所有的配合物在室温下都表现为半导体。采用圆盘扩散法筛选了所有合成的二硫代氨基甲酸酯配体和配合物,以对抗5种人类细菌病原体(大肠杆菌、金黄色葡萄球菌、伤寒沙门氏菌、嗜水气单胞菌和博伊迪志贺菌)。溶剂萃取研究表明,配体在碱性介质(pH = 10) 。图形摘要
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Synthesis, spectroscopic characterization, biological activity, and conducting properties of functionalized Ni(II) dithiocarbamate complexes with solvent extraction studies of the ligands

A series of new nickel(II) dithiocarbamate complexes of general formula [M L2], (where L=benzyl(4-fluorobenzyl)carbamodithioate (L1), benzyl(4-cyanobenzyl)carbamodithioate (L2), ethyl(4-methylbenzyl)carbamodithioate (L3), (4-methoxybenzyl) (naphthalen-1-ylmethyl)carbamodithioate (L4) and ethyl(4-methoxybenzyl)carbamodithioate (L5)) have been synthesized, and characterized via elemental analysis, FT-IR, electronic spectra, 1H NMR, 13C NMR, Mass spectrometry and Thermogravimetric analysis (TGA). The continuous variation method (Job's method) was used to determine the stoichiometry of the complexes. TGA was used to analyze the thermal decomposition behavior of metal complexes in nitrogen atmosphere. As a result of the thermal decomposition process, all of the complexes produced NiS as the final product. X-ray Diffraction (XRD), Energy dispersive X-ray analysis (EDAX), and Transmission electron microscopy (TEM) studies confirm the formation of NiS nanomaterial. Crystalline size of NiS was obtained between 19.97 to 21.35nm range by applying the Scherrer equation using XRD. Solid-state electrical conductivities reveal that all the complexes behave as a semiconductor at room temperature. All the synthesized dithiocarbamate ligands and complexes were screened against five human bacterial pathogens (Escherichia coli, Staphylococcus aureus, Salmonella typhi, Aeromonas hydrophila, and Shigella boydii) by disc diffusion method. Solvent extraction studies show that the ligand has strong extractability towards metal ions in a basic medium (pH=10).

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来源期刊
Journal of Sulfur Chemistry
Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.10
自引率
9.10%
发文量
38
审稿时长
6-12 weeks
期刊介绍: The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.
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