天然气精矿氧化萃取脱硫工业脱硫技术

Tri Partono Adhi, Sardenianto Sardenianto, Antonius Indarto
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引用次数: 0

摘要

在油气生产过程中,除了碳氢化合物外,还会产生许多杂质,包括不同浓度的二氧化碳和硫,这取决于储层的条件和特征以及油气所在的位置。从凝析油中脱硫,常用的技术是HDS(加氢脱硫)。然而,由于工艺要求较高,如高温、高压和大量的氢气消耗,需要一种替代技术来进行这种脱硫。其中一种是氧化萃取法脱硫。需要进一步研究技术和经济评价,以确定在工业规模上应用的可行性。以H2O2/甲酸为氧化剂和催化剂,以DMF为萃取剂,对含硫化合物二苯并噻吩(DBT)的氧化萃取脱硫工艺进行了研究。对于1000桶/天含硫1%-wt的凝析油,成功进行了脱硫,脱硫率为96.55%,凝析油回收率为99.41%。需要9.14美元/桶的处理费,其中化学品的处理费占84%。DMF回收的替代工艺配置成功地将化学成本降低了35.5%,将总处理成本降低了27.0%,达到6.67美元/桶。在该替代工艺配置下,脱硫率达到95.80%,凝析油回收率为99.21%。
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Teknoekonomi Penyingkiran Senyawa Sulfur dari Kondensat Gas Alam dengan Metode Desulfurisasi Oksidatif-Ekstraktif
In the oil and gas production process, apart from hydrocarbons, a number of impurities are produced, including CO2 and sulfur in various concentrations, depending on the conditions and characteristics of the reservoir and the location where the oil and gas is located. To process sulfur removal from condensate, the common technology is HDS (Hydrodesulfurization). However, with process requirements such as high temperature, pressure, and intensive hydrogen consumption, an alternative technology is needed for this desulfurization. One of them is oxidative-extractive desulfurization. Technical and economic evaluations to determine the feasibility of applying on an industrial scale need to be studied further. The study of oxidative-extractive desulfurization process of sulfur compounds (represented as dibenzothiophene, DBT) was carried out using H2O2/formic acid as oxidizing agent and catalyst, as well as extraction with DMF. For a capacity of 1000 bpd of condensate with 1%-wt sulfur, desulfurization was successfully carried out with sulfur removal of 96.55% and condensate recovery of 99.41%. A processing fee of 9.14 USD/barrel is required, of which 84% is required for chemicals. The alternative process configuration for DMF recovery succeeded in reducing chemical costs by 35.5% and reducing total processing costs by 27.0% to 6.67 USD/barrel. In this alternative process configuration, 95.80% sulfur removal was achieved with condensate recovery of 99.21%.
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PENGARUH BATU BATA PRESS SEBAGAI SUBSTITUSI AGREGAT KASAR TERHADAP NILAI KUAT TEKAN BETON ANALISA PENGARUH KEHALUSAN FLY ASH BATUBARA TERHADAP MUTU BETON GEOPOLYMER DARI LIMBAH B3 DENGAN AKTIVATOR POTASSIUM Trans Siginjai ANALISIS POTENSI PERMINTAAN (DEMAND) TRANS SIGINJAI RUTE TELANAI PURA - SENGETI KUAT TEKAN CAMPURAN ROLLER COMPACTED CONCRETE (RCC) DENGAN MENGGUNAKAN SILIKA FUME DAN SUPER PLASTICIZER Kajian Dampak Pajanan Radiasi Panas Saat Terjadi Tumpahan Minyak dan Kebakaran Tangki di Pusat Pengumpul Produksi Minyak PT. X
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