染料敏化太阳能电池中天然染料的提取及光学研究

Specta Pub Date : 2023-08-31 DOI:10.35718/specta.v7i2.868
M. Musyarofah, Budi Prayitno, Nur Aini Fauziyah, Umi Nuraini, Nurrisma Puspitasari
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摘要

利用简单浸渍法和紫外-可见吸收特性对植物叶、花、块茎和果实等部分天然染料的光学性质进行了提取和研究。本研究将样品分为花类(万寿菊、芍药、Centaure、菊花、红花、Gomphrena globosa、Myosotis sylvatica、Lavandula sp.、Clitoria ternatea、洋甘菊、木槿、Rosa sp.);叶片组(芒果、辣木、葡萄、菠菜、柑橘和龙舌兰);块茎和水果类(番茄茄、甜瓜、山竹、姜黄、甜菜和仙人掌)。通过脱水、乙醇浸泡2×24小时、过滤,以一种低成本、简单的方法成功地提取了天然染料的提取物。用紫外-可见分光光度计在400 ~ 700 nm波长范围内观察染料在紫外和可见光范围内的光学性质。各基团的吸收行为在不同波长处表现出优势峰。潜在的,做染料的组合(共敏化:使用多种染料具有不同的吸收光谱,以实现全色响应),以扩大波长吸收染料敏化太阳能电池(DSSC)的应用。
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Extraction and Optical Study of Natural Dyes for Dye-Sensitized Solar Cell Application
Extraction and study of the optical properties of natural dyes from several plant parts such as leaves, flowers, tubers, and fruits have been carried out using a simple maceration method and UV-Vis absorption characterization. The samples were divided into several groups in this study, namely the flower group (Tagetes sp., Paeonia sp., Centaure sp., Chrysanthemum sp., Carthamus tinctorius, Gomphrena globosa, Myosotis sylvatica, Lavandula sp., Clitoria ternatea, Matricaria chamomilla, Hibiscus sabdariffa, and Rosa sp.); the leaf group (Mangifera indica, Moringa oleifera, Graptophyllum pictum, Spinacia oleracea, Citrus hystrix, and Terminalia sp.); and the tuber and fruit group (Solanum lycopersicum, Cucurbita moschata, Garcinia mangostana, Curcuma longa, Beta vulgaris, and Caessapina sp.).  The extract of natural dyes was successfully produced using a low-cost and simple extraction approach via dehydration, immersion for 2×24 hours in ethanol, and followed by filtration. The optical properties of the dyes in UV and visible light range were observed using a UV-Vis spectrophotometer in the wavelength of 400-700 nm. The absorption behaviour showed dominant peaks at different wavelengths for each group. Potentially, to do a combination of dyes (co-sensitization: using more than a dye with different absorption spectra to achieve a panchromatic response) to widen the wavelength absorption for dye-sensitized solar cell (DSSC) applications.
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