聚苯胺负载钯在温和条件下催化还原降解染料

IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Current Green Chemistry Pub Date : 2019-03-31 DOI:10.2174/2213346106666190130101109
Moumita Roy, A. Mondal, Arijit Mondal, A. Das, D. Mukherjee
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引用次数: 11

摘要

采用聚苯胺负载钯催化剂在硼氢化钠存在下还原降解亚甲基蓝、罗丹明B和甲基橙等有机物,是一种环保的方法。深入研究了pH、催化剂用量和催化剂载体的作用,以在环境条件下在几分钟内实现完全有效的降解。催化剂的非均相性质允许通过离心容易地回收,并且催化剂以略微降低的活性再循环五个循环。通过ICP-AES和TEM对回收的催化剂进行了表征,催化剂活性的轻微下降归因于钯纳米颗粒的团聚。
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Polyaniline Supported Palladium Catalyzed Reductive Degradation of Dyes Under Mild Condition
Polyaniline supported palladium catalyst was applied in the reductive degradation of organic dyes such as Methylene Blue, Rhodamine B, and Methyl Orange in presence of sodium borohydride as an environmental-friendly approach. Role of pH, catalyst amount, and catalyst support were investigated thoroughly to achieve complete and efficient degradation within few minutes under ambient condition. Heterogeneous nature of the catalyst allowed easy recovery by centrifugation and the catalyst was recycled for five cycles with slightly reduced activity. Recovered catalyst was characterized by ICP-AES and TEM and a slight decrease in the activity of the catalyst was attributed to the agglomeration of the palladium nanoparticles.
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来源期刊
Current Green Chemistry
Current Green Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.30
自引率
13.60%
发文量
6
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