O. E. Pliusnina, V. Yu. Chevychelov, A. V. Samsonov, A. A. Viryus
{"title":"饱和钾正长岩熔体中氟化物溶解度的实验研究","authors":"O. E. Pliusnina, V. Yu. Chevychelov, A. V. Samsonov, A. A. Viryus","doi":"10.1134/S086959112204004X","DOIUrl":null,"url":null,"abstract":"<p>The paper presents experimental results on the solubility of fluorides in fluid-saturated melt of alkaline ultrapotassic syenite-porphyry from the Gross gold ore deposit in southern Yakutia at <i>T</i> = 600–800°C, <i>P</i> = 150–260 MPa. The experiments were carried out to confirm the assumption of high solubility of fluorine in ultrapotassic syenite melt, which could contribute to the formation of specific and low-viscosity melts that were emplaced in the form of a syenite porphyry sill. The solid products after the experiments contained aluminosilicate glass, potassium feldspar, fluorite, quartz, and two fluoride phases differing in composition (potassium and aluminum fluoride and potassium and magnesium fluoride). The experimental results led us to determine a high maximum solubility of fluorine in the melt: up to 4.2–4.6 wt %, with the maximum F content found in the lowest temperature melt at 625°C. The solidus and liquidus temperatures of the syenite melt were estimated at 600–625 and 650–800°C, respectively. The aqueous fluoride fluid coexisting in equilibrium with the melt was determined to be alkaline. Potassium feldspar was the first to crystallize from the melt in the experiments, which is consistent with what is observed in samples of the naturally occurring rocks.</p>","PeriodicalId":20026,"journal":{"name":"Petrology","volume":"30 4","pages":"418 - 428"},"PeriodicalIF":1.0000,"publicationDate":"2022-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental Study of the Solubility of Fluorides in Fluid-Saturated Potassic Syenite Melt\",\"authors\":\"O. E. Pliusnina, V. Yu. Chevychelov, A. V. Samsonov, A. A. Viryus\",\"doi\":\"10.1134/S086959112204004X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The paper presents experimental results on the solubility of fluorides in fluid-saturated melt of alkaline ultrapotassic syenite-porphyry from the Gross gold ore deposit in southern Yakutia at <i>T</i> = 600–800°C, <i>P</i> = 150–260 MPa. The experiments were carried out to confirm the assumption of high solubility of fluorine in ultrapotassic syenite melt, which could contribute to the formation of specific and low-viscosity melts that were emplaced in the form of a syenite porphyry sill. The solid products after the experiments contained aluminosilicate glass, potassium feldspar, fluorite, quartz, and two fluoride phases differing in composition (potassium and aluminum fluoride and potassium and magnesium fluoride). The experimental results led us to determine a high maximum solubility of fluorine in the melt: up to 4.2–4.6 wt %, with the maximum F content found in the lowest temperature melt at 625°C. The solidus and liquidus temperatures of the syenite melt were estimated at 600–625 and 650–800°C, respectively. The aqueous fluoride fluid coexisting in equilibrium with the melt was determined to be alkaline. Potassium feldspar was the first to crystallize from the melt in the experiments, which is consistent with what is observed in samples of the naturally occurring rocks.</p>\",\"PeriodicalId\":20026,\"journal\":{\"name\":\"Petrology\",\"volume\":\"30 4\",\"pages\":\"418 - 428\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2022-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petrology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S086959112204004X\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petrology","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1134/S086959112204004X","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Experimental Study of the Solubility of Fluorides in Fluid-Saturated Potassic Syenite Melt
The paper presents experimental results on the solubility of fluorides in fluid-saturated melt of alkaline ultrapotassic syenite-porphyry from the Gross gold ore deposit in southern Yakutia at T = 600–800°C, P = 150–260 MPa. The experiments were carried out to confirm the assumption of high solubility of fluorine in ultrapotassic syenite melt, which could contribute to the formation of specific and low-viscosity melts that were emplaced in the form of a syenite porphyry sill. The solid products after the experiments contained aluminosilicate glass, potassium feldspar, fluorite, quartz, and two fluoride phases differing in composition (potassium and aluminum fluoride and potassium and magnesium fluoride). The experimental results led us to determine a high maximum solubility of fluorine in the melt: up to 4.2–4.6 wt %, with the maximum F content found in the lowest temperature melt at 625°C. The solidus and liquidus temperatures of the syenite melt were estimated at 600–625 and 650–800°C, respectively. The aqueous fluoride fluid coexisting in equilibrium with the melt was determined to be alkaline. Potassium feldspar was the first to crystallize from the melt in the experiments, which is consistent with what is observed in samples of the naturally occurring rocks.
期刊介绍:
Petrology is a journal of magmatic, metamorphic, and experimental petrology, mineralogy, and geochemistry. The journal offers comprehensive information on all multidisciplinary aspects of theoretical, experimental, and applied petrology. By giving special consideration to studies on the petrography of different regions of the former Soviet Union, Petrology provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.