Arghya Dutta, Abhinandan Mahanta, Subhra Jyoti Panda, Soumya Biswas, Vinayak B Kamble, Chandra Shekhar Purohit, SK Jasimuddin, Rajarshi Ghosh
{"title":"以三(1,10-菲罗啉)镍(II)为反阳离子的半导体镍(II)二硫代酸盐的合成、x射线结构表征和电化学研究","authors":"Arghya Dutta, Abhinandan Mahanta, Subhra Jyoti Panda, Soumya Biswas, Vinayak B Kamble, Chandra Shekhar Purohit, SK Jasimuddin, Rajarshi Ghosh","doi":"10.1007/s12039-023-02179-w","DOIUrl":null,"url":null,"abstract":"<div><p>An ion-pair complex [Ni(<i>o</i>-phen)<sub>3</sub>][Ni(L)<sub>2</sub>]<sub>2</sub>.CH<sub>2</sub>Cl<sub>2</sub> (<b>1</b>) [L = 1,2-diphenylethylene-1,2-dithiolate, <i>o</i>-phen = 1,10-phenanthroline] has been synthesized and X-ray crystallographically characterized. The solution structure of <b>1</b>, as derived from cyclic voltammetry, conforms well to the solid-state molecular structure. The redox peaks obtained from the electrochemical analysis of <b>1</b> are to some extent a combination of the peaks obtained individually for [Ni(<i>o</i>-phen)<sub>3</sub>]<sup>2+</sup> and [Ni(L)<sub>2</sub>]. Moreover, the reaction protocol for the synthesis of the title complex by the addition of <i>o</i>-phen to [Ni(L)<sub>2</sub>] is analyzed electrochemically. <b>1</b> conducts electricity in solid-state. The electrical conductivity varied on varying temperatures from 308 K (35 °C) to 423 K (150 °C). The compound is found to be thermally unstable after 150 °C.</p><h3>Graphical abstract</h3><p>An ion-pair complex [Ni(<i>o</i>-phen)<sub>3</sub>][Ni(L)<sub>2</sub>]<sub>2</sub>.CH<sub>2</sub>Cl<sub>2</sub> (<b>1</b>) [L = 1,2-diphenylethylene-1,2-dithiolate] has been synthesized and characterized by X-ray crystallography. On electrochemical characterization in solution, the redox peaks (reduction) obtained from the cyclic voltammetry of <b>1</b> are found to be a combination of the peaks obtained individually for [Ni(<i>o</i>-phen)<sub>3</sub>]<sup>2+</sup> and [Ni(L)<sub>2</sub>]. <b>1</b> also conducts electricity in a solid state like a semiconducting material.\n</p><figure><div><div><div><picture><source><img></source></picture></div></div></div></figure></div>","PeriodicalId":50242,"journal":{"name":"Journal of Chemical Sciences","volume":"135 3","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2023-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, X-ray structural characterization, and electrochemical investigations on a semiconducting Ni(II) dithiolate with tris(1,10-phenanthroline)nickel(II) as counter-cation\",\"authors\":\"Arghya Dutta, Abhinandan Mahanta, Subhra Jyoti Panda, Soumya Biswas, Vinayak B Kamble, Chandra Shekhar Purohit, SK Jasimuddin, Rajarshi Ghosh\",\"doi\":\"10.1007/s12039-023-02179-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An ion-pair complex [Ni(<i>o</i>-phen)<sub>3</sub>][Ni(L)<sub>2</sub>]<sub>2</sub>.CH<sub>2</sub>Cl<sub>2</sub> (<b>1</b>) [L = 1,2-diphenylethylene-1,2-dithiolate, <i>o</i>-phen = 1,10-phenanthroline] has been synthesized and X-ray crystallographically characterized. The solution structure of <b>1</b>, as derived from cyclic voltammetry, conforms well to the solid-state molecular structure. The redox peaks obtained from the electrochemical analysis of <b>1</b> are to some extent a combination of the peaks obtained individually for [Ni(<i>o</i>-phen)<sub>3</sub>]<sup>2+</sup> and [Ni(L)<sub>2</sub>]. Moreover, the reaction protocol for the synthesis of the title complex by the addition of <i>o</i>-phen to [Ni(L)<sub>2</sub>] is analyzed electrochemically. <b>1</b> conducts electricity in solid-state. The electrical conductivity varied on varying temperatures from 308 K (35 °C) to 423 K (150 °C). The compound is found to be thermally unstable after 150 °C.</p><h3>Graphical abstract</h3><p>An ion-pair complex [Ni(<i>o</i>-phen)<sub>3</sub>][Ni(L)<sub>2</sub>]<sub>2</sub>.CH<sub>2</sub>Cl<sub>2</sub> (<b>1</b>) [L = 1,2-diphenylethylene-1,2-dithiolate] has been synthesized and characterized by X-ray crystallography. On electrochemical characterization in solution, the redox peaks (reduction) obtained from the cyclic voltammetry of <b>1</b> are found to be a combination of the peaks obtained individually for [Ni(<i>o</i>-phen)<sub>3</sub>]<sup>2+</sup> and [Ni(L)<sub>2</sub>]. <b>1</b> also conducts electricity in a solid state like a semiconducting material.\\n</p><figure><div><div><div><picture><source><img></source></picture></div></div></div></figure></div>\",\"PeriodicalId\":50242,\"journal\":{\"name\":\"Journal of Chemical Sciences\",\"volume\":\"135 3\",\"pages\":\"\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-06-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12039-023-02179-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s12039-023-02179-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}
Synthesis, X-ray structural characterization, and electrochemical investigations on a semiconducting Ni(II) dithiolate with tris(1,10-phenanthroline)nickel(II) as counter-cation
An ion-pair complex [Ni(o-phen)3][Ni(L)2]2.CH2Cl2 (1) [L = 1,2-diphenylethylene-1,2-dithiolate, o-phen = 1,10-phenanthroline] has been synthesized and X-ray crystallographically characterized. The solution structure of 1, as derived from cyclic voltammetry, conforms well to the solid-state molecular structure. The redox peaks obtained from the electrochemical analysis of 1 are to some extent a combination of the peaks obtained individually for [Ni(o-phen)3]2+ and [Ni(L)2]. Moreover, the reaction protocol for the synthesis of the title complex by the addition of o-phen to [Ni(L)2] is analyzed electrochemically. 1 conducts electricity in solid-state. The electrical conductivity varied on varying temperatures from 308 K (35 °C) to 423 K (150 °C). The compound is found to be thermally unstable after 150 °C.
Graphical abstract
An ion-pair complex [Ni(o-phen)3][Ni(L)2]2.CH2Cl2 (1) [L = 1,2-diphenylethylene-1,2-dithiolate] has been synthesized and characterized by X-ray crystallography. On electrochemical characterization in solution, the redox peaks (reduction) obtained from the cyclic voltammetry of 1 are found to be a combination of the peaks obtained individually for [Ni(o-phen)3]2+ and [Ni(L)2]. 1 also conducts electricity in a solid state like a semiconducting material.
期刊介绍：
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.
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