植物源碳化生物聚合物的吸附性能

IF 6.4 3区 环境科学与生态学 Q2 ENERGY & FUELS Carbon Resources Conversion Pub Date : 2023-03-01 DOI:10.1016/j.crcon.2022.10.004
A.P. Karmanov , A.P. Voznyakovsky , L.S. Kocheva , N.G. Rachkova , N.I. Bogdanovich
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引用次数: 2

摘要

对木质纤维素生物质合成碳纳米材料(CNM)、天然木质素和技术木质素进行了研究。本研究首次提出利用侵染性最强、毒性最强的大猪草(Sosnovsky hogweed)的茎段生产CNM。考察了原料选择和合成条件对样品吸附性能和表面多孔性的影响。确定了低浓度(0.625 μg/ml)铀水溶液吸附过程的主要规律。我们发现碳化生物聚合物(CBP)样品具有很强的铀潴留特征,其中大量(67-70%)不被水或CH3COONH4和HCI (1 M)水溶液解吸。此外,我们发现我们合成的碳纳米材料可以吸附真菌毒素T-2。研究结果表明CNM具有很高的创新潜力。
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Sorption properties of carbonized biopolymers of plant origin

Studies of carbon nanomaterials (CNM) synthesized from lignocellulosic biomass, and natural and technical lignins were carried out. For the first time, we suggested using stems of Sosnovsky hogweed, one of the most aggressive and poisonous invasive plant species, to produce CNM. The influence of the choice of raw materials and synthesis conditions on the sorption and surface-porous characteristics of the samples was evaluated. The main regularities of adsorption processes from aqueous media with a low concentration (0.625 μg/ml) of uranium were established. We found that strong retention of uranium characterizes carbonized biopolymers (CBP) samples, a significant amount of which (67–70%) is not desorbed either by water or aqueous solutions of CH3COONH4 and HCI (1 M). In addition, we found out that the carbon nanomaterials we synthesized can adsorb mycotoxin T-2. The obtained results indicated a high innovative potential of CNM.

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来源期刊
Carbon Resources Conversion
Carbon Resources Conversion Materials Science-Materials Science (miscellaneous)
CiteScore
9.90
自引率
11.70%
发文量
36
审稿时长
10 weeks
期刊介绍: Carbon Resources Conversion (CRC) publishes fundamental studies and industrial developments regarding relevant technologies aiming for the clean, efficient, value-added, and low-carbon utilization of carbon-containing resources as fuel for energy and as feedstock for materials or chemicals from, for example, fossil fuels, biomass, syngas, CO2, hydrocarbons, and organic wastes via physical, thermal, chemical, biological, and other technical methods. CRC also publishes scientific and engineering studies on resource characterization and pretreatment, carbon material innovation and production, clean technologies related to carbon resource conversion and utilization, and various process-supporting technologies, including on-line or off-line measurement and monitoring, modeling, simulations focused on safe and efficient process operation and control, and process and equipment optimization.
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