锯齿形流道质子交换膜燃料电池性能的数值研究

Shuanyang Zhang, Shun Liu, Hongtao Xu, Y. Mao, Ke Wang
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引用次数: 1

摘要

合理的流道设计对提高质子交换膜燃料电池(PEMFC)的性能起着重要作用。本文研究了三种不同匝数的锯齿形流道对PEMFC性能的影响。对极化曲线、氧和水的摩尔浓度以及功率密度进行了分析,数值结果表明,锯齿形流道的整体性能明显优于传统的平行流道。随着匝数从3匝增加到9匝,PEMFC的性能逐渐提高,氧向电化学反应界面的扩散能力也得到了提高,低氧浓度区域逐渐减少。当匝数为9时,在0.4V的工作电压下,PEMFC的电流密度比传统并联沟道的电流密度高8.85%,并且气体扩散层(GDL)和催化剂层(CL)界面处的氧不均匀性最小,值为0.51。此外,通道中的水的摩尔浓度也降低了。由于锯齿形流道阻力较大,锯齿形流道的最大压降为263.5Pa,这也有利于提高传统平行流道的排水效果。随着锯齿形通道匝数的增加,压降和寄生功率密度逐渐增加。9字形流道的最大压降和净功率密度分别为263.5Pa和2995.6W/m2。
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Numerical Investigation on the Performance of Proton Exchange Membrane Fuel Cell With Zigzag Flow Channels
Reasonable flow channel designs play a significant role in improving the performance of proton exchange membrane fuel cells (PEMFC). The effect of the zigzag flow channels with three different numbers of turns on the performance of PEMFC was investigated in this paper. The polarization curves, molar concentration of oxygen and water, and power density were analyzed, and the numerical results showed that the overall performance of the zigzag flow channels was significantly better than that of the conventional parallel flow channel. With the increase of the number of turns from 3 to 9, the performance of PEMFC was gradually improved, the diffusion capacity of oxygen to the interface of the electrochemical reaction was also promoted, and the low oxygen concentration regions were gradually reduced. When the number of turns was 9, the current density of PEMFC was 8.85% higher than that of the conventional parallel channel at the operating voltage of 0.4 V, and the oxygen non-uniformity at the between gas diffusion layer (GDL) and catalyst layer (CL) interface was the minimum with a value of 0.51. In addition, the molar concentration of water in the channel also decreased. Due to the relatively large resistance of the zigzag flow channels, the maximum pressure drop of the zigzag flow channel was 263.5 Pa, which was also conducive to the improvement of the drainage effect of the conventional parallel flow channel. With the increase of the number of turns in the zigzag channel, the pressure drop and parasitic power density gradually increased. The 9-zigzag flow channel obtained the maximum pressure drop and net power density, which were 263.5 Pa and 2995.6 W/m2, respectively.
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