用改性羊毛去除水溶液中的Cr(III)

Ganchimeg Yunden, N. Kano, Hee-Joon Kim
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引用次数: 3

摘要

采用马来酸酐在不同温度下对蒙古羊毛进行改性,获得了新型的Cr(III)去除吸附剂。在间歇系统中研究了改性羊毛对水溶液中Cr(III)的吸附。本工作采用电感耦合等离子体发射光谱法(ICP-OES)测定了pH、接触时间、温度和初始浓度等参数对吸附容量的影响。用扫描电子显微镜(SEM)和傅立叶变换红外光谱仪(FT-IR)对改性羊毛进行了表征。进行了热力学和动力学研究,结果证实吸附过程本质上是自发的、热力学上有利的和吸热的。在动力学上,吸附过程服从拟二阶模型。改性羊毛可以作为从水溶液中去除Cr(III)的有效吸附剂。
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The Removal of Cr(III) from Aqueous Solution Using Modified Wool
Mongolian sheep wool was modified by maleic anhydride at different temperatures to obtain new adsorbent for the removal of Cr(III). Adsorption of Cr(III) from aqueous solution onto the modified wool was investigated in batch system. In this work, the effect of various parameters such as pH, contact time, temperature and initial concentration on the adsorption capacity was determined by ICP-OES (Inductively Coupled Plasma-Optical Emission Spectrometry). Modified wool was characterized by SEM (scanning electron microscopy) and FT-IR (Fourier transform infrared spectrometer). The thermodynamic and kinetic studies were carried out and the results confirmed that the adsorption process was spontaneous in nature, thermodynamically favourable and endothermic. Kinetically, the adsorption process obeys the pseudo-second order model. The modified wool can be an effective adsorbent for the removal of Cr(III) from aqueous solution.
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