{"title":"聚集增强发射橙色碳点,用于信息加密和检测Fe3+和四环素。","authors":"Chunyan Li, Lei Liu, Daohan Zhang","doi":"10.1016/j.saa.2023.123504","DOIUrl":null,"url":null,"abstract":"<p><p>In this study, N-doped fluorescent carbon dots with aggregation enhanced emission (N-CDs) were synthesized by a simple and rapid microwave-assisted method using o-phenylenediamine (OPD) and urea as raw materials and water as solvent. The fluorescence quantum yield of N-CDs was 20.64 %. N-CDs can be applied as invisible inks for message encryption. Furthermore, the fluorescence intensity of N-CDs can be quenched by Fe<sup>3+</sup> and enhanced by tetracycline (TC). Therefore, two fluorescent probes were simultaneously designed in this study. Namely, \"turn-off\" fluorescence probe for Fe<sup>3+</sup> and \"turn-on\" fluorescence probe for TC. The linear detection range of Fe<sup>3+</sup> is from 1 to 70 μM, and detection limit is 0.1011 μM; the linear detection range of TC is from 0.1 to 10 μM, and the detection limit can be as low as 0.0555 μM. In this paper, the mutual interference between Fe<sup>3+</sup> and TC was investigated for the first time. The detection of Fe<sup>3+</sup> and TC was made more accurate by optimizing pH conditions and adding masking agent.</p>","PeriodicalId":94213,"journal":{"name":"Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy","volume":"305 ","pages":"123504"},"PeriodicalIF":0.0000,"publicationDate":"2024-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Aggregation enhanced emissive orange carbon dots for information encryption and detection of Fe<sup>3+</sup> and tetracycline.\",\"authors\":\"Chunyan Li, Lei Liu, Daohan Zhang\",\"doi\":\"10.1016/j.saa.2023.123504\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In this study, N-doped fluorescent carbon dots with aggregation enhanced emission (N-CDs) were synthesized by a simple and rapid microwave-assisted method using o-phenylenediamine (OPD) and urea as raw materials and water as solvent. The fluorescence quantum yield of N-CDs was 20.64 %. N-CDs can be applied as invisible inks for message encryption. Furthermore, the fluorescence intensity of N-CDs can be quenched by Fe<sup>3+</sup> and enhanced by tetracycline (TC). Therefore, two fluorescent probes were simultaneously designed in this study. Namely, \\\"turn-off\\\" fluorescence probe for Fe<sup>3+</sup> and \\\"turn-on\\\" fluorescence probe for TC. The linear detection range of Fe<sup>3+</sup> is from 1 to 70 μM, and detection limit is 0.1011 μM; the linear detection range of TC is from 0.1 to 10 μM, and the detection limit can be as low as 0.0555 μM. In this paper, the mutual interference between Fe<sup>3+</sup> and TC was investigated for the first time. The detection of Fe<sup>3+</sup> and TC was made more accurate by optimizing pH conditions and adding masking agent.</p>\",\"PeriodicalId\":94213,\"journal\":{\"name\":\"Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy\",\"volume\":\"305 \",\"pages\":\"123504\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1016/j.saa.2023.123504\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2023/10/16 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.saa.2023.123504","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2023/10/16 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
Aggregation enhanced emissive orange carbon dots for information encryption and detection of Fe3+ and tetracycline.
In this study, N-doped fluorescent carbon dots with aggregation enhanced emission (N-CDs) were synthesized by a simple and rapid microwave-assisted method using o-phenylenediamine (OPD) and urea as raw materials and water as solvent. The fluorescence quantum yield of N-CDs was 20.64 %. N-CDs can be applied as invisible inks for message encryption. Furthermore, the fluorescence intensity of N-CDs can be quenched by Fe3+ and enhanced by tetracycline (TC). Therefore, two fluorescent probes were simultaneously designed in this study. Namely, "turn-off" fluorescence probe for Fe3+ and "turn-on" fluorescence probe for TC. The linear detection range of Fe3+ is from 1 to 70 μM, and detection limit is 0.1011 μM; the linear detection range of TC is from 0.1 to 10 μM, and the detection limit can be as low as 0.0555 μM. In this paper, the mutual interference between Fe3+ and TC was investigated for the first time. The detection of Fe3+ and TC was made more accurate by optimizing pH conditions and adding masking agent.