高含水量酒精萃取药渣的流化床燃烧及掺混废活性焦炭的影响

IF 6.4 3区 环境科学与生态学 Q2 ENERGY & FUELS Carbon Resources Conversion Pub Date : 2023-03-01 DOI:10.1016/j.crcon.2022.09.003
Xuan Liu , Xinyu Zhu , Wenyan Wang , Bowen Shi , Guangyi Zhang , Jianling Zhang , Jiancheng Yang , Yanming Shen
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引用次数: 0

摘要

利用秸秆燃烧进行热回收是一种很好的利用方式,但烟气中存在高浓度NOx排放问题。以乙醇提取的草药残渣(AEHR)为对象,在流化床反应器中立即燃烧,研究其NOx排放特性。结果表明,烟气中的大部分NOx是由炭氮(CN)产生的;随着燃料水含量的增加,NOx排放浓度呈现出先降低后增加的趋势;在确保充分燃烧的前提下,适当低的燃烧温度抑制了NOx排放。采用空气分级燃烧有效控制NOx:与传统燃烧相比,烟气中NOx排放浓度降低至296 mg·m−3,NOx减排率达到46.51%。通过将废弃的活性焦炭(WAC)掺入AEHR中进行共燃烧,既有助于稳定燃烧状态,又有助于进一步减少NOx排放。当WAC的混合比例在20–30%的适当范围内时,烟气中的NOx排放浓度低至231.4 mg·m−3。除了混合WAC的燃烧烟气的稀释作用外,其不完全燃烧引起的局部还原气氛及其强大的吸收能力和催化作用也是NOx排放浓度进一步降低的原因。
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Fluidized bed combustion of high water content alcohol extracted herb residue and the impacts of blending wasted activated coke

Combustion of herb residues (HRs) for heat recovery is a good way for their utilization, but there exists such a problem as high concentration NOx emission in flue gas. The alcohol extracted herb residue (AEHR), one special type of HRs, was chosen as the object and was subjected to immediate combustion in a fluidized bed reactor to investigate the characteristics of its resulting NOx emission. The results showed that, most of the NOx in the flue gas was produced from the char nitrogen (CN); as the fuel water content increased, the NOx emission concentration exhibited a trend of first decreasing and then increasing; and a properly low combustion temperature inhibited the NOx emission upon the premise of ensuring full combustion. Air staging combustion was adopted to effectively control NOx: the NOx emission concentration in the flue gas was reduced to 296 mg·m−3 and the NOx emission reduction rate reached 46.51 % compared to conventional combustion. Co-combustion by blending wasted activated coke (WAC) into the AEHR helped both stabilize the combustion state and reduce further the NOx emission. When the blending ratio of WAC fell within a proper range of 20–30 %, the NOx emission concentration in the flue gas was as low as 231.4 mg·m−3. In addition to the dilution effect of the combustion flue gas of the blended WAC, the local reducing atmosphere caused by its incomplete combustion as well as its strong absorbability and catalytical effect was accountable for the further decrease of the NOx emission concentration.

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来源期刊
Carbon Resources Conversion
Carbon Resources Conversion Materials Science-Materials Science (miscellaneous)
CiteScore
9.90
自引率
11.70%
发文量
36
审稿时长
10 weeks
期刊介绍: Carbon Resources Conversion (CRC) publishes fundamental studies and industrial developments regarding relevant technologies aiming for the clean, efficient, value-added, and low-carbon utilization of carbon-containing resources as fuel for energy and as feedstock for materials or chemicals from, for example, fossil fuels, biomass, syngas, CO2, hydrocarbons, and organic wastes via physical, thermal, chemical, biological, and other technical methods. CRC also publishes scientific and engineering studies on resource characterization and pretreatment, carbon material innovation and production, clean technologies related to carbon resource conversion and utilization, and various process-supporting technologies, including on-line or off-line measurement and monitoring, modeling, simulations focused on safe and efficient process operation and control, and process and equipment optimization.
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Outside Front Cover Outside Back Cover Developments and challenges on enhancement of photocatalytic CO2 reduction through photocatalysis Outside Front Cover Outside Back Cover
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