卟啉金属-有机框架的生物应用

Li-Jian Chen , Xu Zhao , Xiu-Ping Yan
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引用次数: 0

摘要

卟啉及其衍生物由于其光物理和电化学性质,在各个领域得到了广泛的应用。然而,在水性介质中自聚集和自猝灭的缺点限制了它们的生物学应用。卟啉类金属有机框架(PMOF)由于将卟啉作为有机连接体引入框架中克服了游离卟啉的局限性而引起了人们的极大关注。本文综述了PMOF的构建策略及其生物学应用。还讨论了这类新兴材料所面临的挑战和机遇。
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Porphyrinic metal-organic frameworks for biological applications

Porphyrins and their derivatives have been extensively applied in various fields owing to their photophysical and electrochemical properties. However, the drawbacks of self-aggregation and self-quenching in aqueous media limit their biological applications. Porphyrinic metal-organic frameworks (PMOFs) have attracted considerable attention because the introduction of porphyrins as organic linker into frameworks overcomes the limitations of free porphyrins. This review summarizes the strategies for the construction of PMOFs and their biological applications. The challenges and chances displayed by this class of emerging materials are also discussed.

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