{"title":"含硫油微量元素组成中钒占主导地位的可能原因","authors":"G. V. Lisichkin","doi":"10.3103/S0027131422070094","DOIUrl":null,"url":null,"abstract":"<p>In accordance with the abiogenic hypothesis of the origin of oil, deposits formed as a result of degassing of the Earth, in particular, due to the interaction of mantle methane and its polycondensation products with elemental sulfur, are thermodynamically open systems. In open systems, self-organization processes are realized and a progressive evolution of the catalyst of the basic reaction occurs, accompanied by an increase in its activity and accumulation in the system. The predominance of vanadium in the trace element composition of sour oils may be due to its catalytic activity in the basic reaction of the formation of C–S bonds.</p>","PeriodicalId":709,"journal":{"name":"Moscow University Chemistry Bulletin","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Possible Reason for the Predomination of Vanadium in the Microelement Composition of Sulfurous Oils\",\"authors\":\"G. V. Lisichkin\",\"doi\":\"10.3103/S0027131422070094\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In accordance with the abiogenic hypothesis of the origin of oil, deposits formed as a result of degassing of the Earth, in particular, due to the interaction of mantle methane and its polycondensation products with elemental sulfur, are thermodynamically open systems. In open systems, self-organization processes are realized and a progressive evolution of the catalyst of the basic reaction occurs, accompanied by an increase in its activity and accumulation in the system. The predominance of vanadium in the trace element composition of sour oils may be due to its catalytic activity in the basic reaction of the formation of C–S bonds.</p>\",\"PeriodicalId\":709,\"journal\":{\"name\":\"Moscow University Chemistry Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-03-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Moscow University Chemistry Bulletin\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S0027131422070094\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Moscow University Chemistry Bulletin","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S0027131422070094","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Possible Reason for the Predomination of Vanadium in the Microelement Composition of Sulfurous Oils
In accordance with the abiogenic hypothesis of the origin of oil, deposits formed as a result of degassing of the Earth, in particular, due to the interaction of mantle methane and its polycondensation products with elemental sulfur, are thermodynamically open systems. In open systems, self-organization processes are realized and a progressive evolution of the catalyst of the basic reaction occurs, accompanied by an increase in its activity and accumulation in the system. The predominance of vanadium in the trace element composition of sour oils may be due to its catalytic activity in the basic reaction of the formation of C–S bonds.
期刊介绍：
Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.
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