涉及金基光催化的近代化学转化

Vishal Srivastava , Surabhi Sinha , Deepak Kumar , Praveen P. Singh
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引用次数: 3

摘要

金光催化包括一组不同的金催化过程,具有本质上不同的基本阶段。当光催化和金催化相结合时,在不使用化学计量牺牲的外源氧化剂的情况下,通过电子转移和自由基添加来改变金中心的价态。自由基与金催化剂的特殊相容性使许多重要的有机转化成为可能。使用金络合物的光催化为金化学开辟了新的机会,并令人钦佩地补充了现有的光氧化还原催化技术。在这篇综述中,用许多有趣的技术讨论了单核金(I)催化剂(包括有光敏剂和没有光敏剂的催化剂)和双核金(Ⅰ)光催化剂的转化,以及它们对有机化学家的意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Neoteric chemical transformation involving gold based photocatalysis

Gold photocatalysis includes a diverse set of gold-catalyzed processes with essentially distinctive fundamental stages. When photocatalysis and gold catalysis are combined, then it results to change the valence of the gold centre by electron transfer and radical addition without the usage of exogenous oxidants that are stoichiometrically sacrificed. A number of significant organic transformations are made possible by radicals' exceptional compatibility with gold catalysts. The photocatalysis using gold complexes opens up new opportunities for gold chemistry and complements the existing photoredox catalysis techniques admirably. In this review, the achieved transformations for mononuclear gold(I) catalysts (both those with and without a photosensitizer) and dinuclear gold(I) photocatalysts are discussed with a number of fascinating techniques, as well as their significance for organic chemists.

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