聚琥珀酸丁二烯-共琥珀酸六亚乙烯单体组成对茄枯镰刀菌表皮酶水解的影响

IF 1.7 4区 工程技术 Q4 POLYMER SCIENCE International Journal of Polymer Analysis and Characterization Pub Date : 2023-01-01 DOI:10.1080/1023666X.2022.2143770
Ting Hu , Yujun Wang , Jingwei Lin , Zhanyong Wang
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引用次数: 0

摘要

用镰刀菌角质酶对聚丁二酸丁二醇酯(PBS)、聚丁二酸六亚甲基酯(PHS)和三种聚丁二酸丁二醇酯-共-六亚甲基酯进行了酶解。结果表明,这些聚酯的酶水解特性主要受结晶度、热性能和BS/HS比的影响。聚酯的酶解速率如下:P(BS-co-HS52)≈P(BS-co-HS71) >; PHS >; P(BS-co-HS32) >; PBS。此外,随着HS含量的增加,聚酯的结晶度(Xc)和熔融温度(Tm)都先降低后升高。P(BS-co-HS52)和P(BS-co-HS71)具有最低的Xc和最低的Tm,因此具有最高的水解速率;结果还表明,BS/HS比对聚酯的物理性能和降解性能有影响。因此,通过调节BS/HS比例,可以制备具有各种物理性能和可降解性的聚酯,用于不同的应用。聚酯的结晶区和无定形区都被水解,在此过程中部分结晶区被转化为无定形区。最后,我们发现聚酯的晶体结构和热稳定性不受酶水解的影响。
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Influence of monomer composition of poly(butylene succinate-co-hexamethylene succinate)s on their enzymatic hydrolysis by Fusarium solani cutinase

Poly(butylene succinate) (PBS), poly(hexamethylene succinate) (PHS) and three kinds of poly(butylene succinate-co-hexamethylene succinate)s (P(BS-co-HS)s) were enzymatically hydrolyzed by Fusarium solani cutinase. The results showed that the characteristics of the enzymatic hydrolysis of these polyesters were mainly affected by crystallinity, thermal properties and the BS/HS ratio. The enzymatic hydrolysis rates of the polyesters are as follows: P(BS-co-HS52) ≈ P(BS-co-HS71) > PHS > P(BS-co-HS32) > PBS. Furthermore, with increasing HS content, both the degree of crystallinity (Xc) and melting temperature (Tm) of the polyesters first decreased and then increased. P(BS-co-HS52) and P(BS-co-HS71) had the lowest Xc and the lowest Tm, thus had the highest hydrolysis rate; this shows that the hydrolysis rate is affected by Xc and Tm. The results also showed that BS/HS ratio could affect the physical properties and degradability of polyesters. Thus, it is possible to prepare polyesters with various physical properties and degradability for different applications by adjusting BS/HS ratio. The crystalline and amorphous regions of the polyesters were both hydrolyzed, during which parts of the crystalline regions were converted into the amorphous regions. Finally, we found that the crystal structure and thermal stability of the polyesters were not affected by the enzymatic hydrolysis.

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来源期刊
CiteScore
3.50
自引率
5.30%
发文量
37
审稿时长
1.6 months
期刊介绍: The scope of the journal is to publish original contributions and reviews on studies, methodologies, instrumentation, and applications involving the analysis and characterization of polymers and polymeric-based materials, including synthetic polymers, blends, composites, fibers, coatings, supramolecular structures, polysaccharides, and biopolymers. The Journal will accept papers and review articles on the following topics and research areas involving fundamental and applied studies of polymer analysis and characterization: Characterization and analysis of new and existing polymers and polymeric-based materials. Design and evaluation of analytical instrumentation and physical testing equipment. Determination of molecular weight, size, conformation, branching, cross-linking, chemical structure, and sequence distribution. Using separation, spectroscopic, and scattering techniques. Surface characterization of polymeric materials. Measurement of solution and bulk properties and behavior of polymers. Studies involving structure-property-processing relationships, and polymer aging. Analysis of oligomeric materials. Analysis of polymer additives and decomposition products.
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